Cargando…

Iron‐Catalyzed Cross‐Coupling of Thioesters and Organomanganese Reagents

We report a Fukuyama‐type coupling of thioesters with aliphatic organomanganese reagents utilizing a cheap and easily available iron(III) precatalyst. The reactions exhibit a wide tolerance of solvents and functional groups, allowing for the conversion of thioesters derived from natural products and...

Descripción completa

Detalles Bibliográficos
Autores principales:	Geiger, Valentin Jacob, Lefèvre, Guillaume, Fleischer, Ivana
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804419/ https://www.ncbi.nlm.nih.gov/pubmed/35869871 http://dx.doi.org/10.1002/chem.202202212

Ejemplares similares

Mechanistic Investigations of Ruthenium Catalyzed Dehydrogenative Thioester Synthesis and Thioester Hydrogenation
por: Rauch, Michael, et al.
Publicado: (2021)

Iron‐catalyzed Cross‐Coupling of Propargyl Carboxylates and Grignard Reagents: Synthesis of Substituted Allenes
por: Kessler, Simon N., et al.
Publicado: (2016)

Iron‐Catalyzed Cross‐Coupling of Alkynyl and Styrenyl Chlorides with Alkyl Grignard Reagents in Batch and Flow
por: Deng, Yuchao, et al.
Publicado: (2019)

Iron‐Catalyzed Cross‐Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols
por: Posevins, Daniels, et al.
Publicado: (2021)

Palladium/Norbornene-Catalyzed Decarbonylative Difunctionalization of Thioesters
por: Han, Ming-Liang, et al.
Publicado: (2021)

Iron-Catalyzed Cross-Coupling of α-Allenyl Esters with Grignard Reagents for the Synthesis of 1,3-Dienes
por: Kong, Wei-Jun, et al.
Publicado: (2023)

Recent Advance in Heterocyclic Organozinc and Organomanganese Compounds; Direct Synthetic Routes and Application in Organic Synthesis
por: Kim, Seung-Hoi, et al.
Publicado: (2010)

A Synthesis of Substituted α-Allenols via Iron-Catalyzed Cross-Coupling of Propargyl Carboxylates with Grignard Reagents
por: Kessler, Simon N., et al.
Publicado: (2016)

Hypervalent Iodine Reagents in Palladium-Catalyzed Oxidative Cross-Coupling Reactions
por: Shetgaonkar, Samata E., et al.
Publicado: (2020)

Iron-Catalyzed Cross-Coupling of Bis-(aryl)manganese Nucleophiles with Alkenyl Halides: Optimization and Mechanistic Investigations
por: Rousseau, Lidie, et al.
Publicado: (2020)

Iron-Catalyzed C(sp(2))–C(sp(3)) Cross-Coupling of Aryl Chlorobenzoates with Alkyl Grignard Reagents
por: Bisz, Elwira, et al.
Publicado: (2020)

Carboxylate Catalyzed Isomerization of β,γ‐Unsaturated N‐Acetylcysteamine Thioesters
por: Riuttamäki, Saara, et al.
Publicado: (2022)

Palladium-catalyzed intermolecular transthioetherification of aryl halides with thioethers and thioesters
por: Li, Yahui, et al.
Publicado: (2020)

Iron-Catalyzed Coupling of Aryl Grignard Reagents with Alkyl Halides: A Competitive Hammett Study**
por: Hedström, Anna, et al.
Publicado: (2011)

Copper-Catalyzed Oxidative Homo- and Cross-Coupling of Grignard Reagents Using Diaziridinone
por: Zhu, Yingguang, et al.
Publicado: (2014)

Cobalt‐Catalyzed Cross‐Coupling of Functionalized Alkylzinc Reagents with (Hetero)Aryl Halides
por: Lutter, Ferdinand H., et al.
Publicado: (2020)

Copper(I)-Catalyzed Cross-Coupling of 1-Bromoalkynes with N-Heterocyclic Organozinc Reagents
por: Frabitore, Christian, et al.
Publicado: (2022)

Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides
por: Yang, Yang, et al.
Publicado: (2014)

Efficient Pd‐Catalyzed Direct Coupling of Aryl Chlorides with Alkyllithium Reagents
por: Scherpf, Thorsten, et al.
Publicado: (2020)

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers with Isotopically-Labeled Grignard Reagents
por: Dawson, David D., et al.
Publicado: (2015)

Cross-Coupling Reaction of Allylic Ethers with Aryl Grignard Reagents Catalyzed by a Nickel Pincer Complex
por: Hashimoto, Toru, et al.
Publicado: (2019)

Rhodium‐Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
por: Ochiai, Hidenori, et al.
Publicado: (2017)

Non-Palladium-Catalyzed Oxidative Coupling Reactions Using Hypervalent Iodine Reagents
por: Shetgaonkar, Samata E., et al.
Publicado: (2022)

Triorganoindium Reagents in Rh-Catalyzed C–H Activation/C–C Cross-Coupling Reactions of 2-Arylpyridines
por: Riveiros, Ricardo, et al.
Publicado: (2018)

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds
por: Cherney, Alan H., et al.
Publicado: (2015)

Nickel-catalyzed C–N bond activation: activated primary amines as alkylating reagents in reductive cross-coupling
por: Yue, Huifeng, et al.
Publicado: (2019)

Active template rotaxane synthesis through the Ni-catalyzed cross-coupling of alkylzinc reagents with redox-active esters
por: Echavarren, Javier, et al.
Publicado: (2019)

Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide
por: Weng, Yangyang, et al.
Publicado: (2020)

Mg(2+)-Imidazole-Catalyzed Self-Condensation of Malonyl Thioesters: Getting Tuned for Biomimetic Polyketide Synthesis?
por: Sakai, Naomi, et al.
Publicado: (2001)

Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignards with Aryl Chlorobenzenesulfonates
por: Bisz, Elwira
Publicado: (2021)

A DFT Study on Fe(I)/Fe(II)/Fe(III) Mechanism of the Cross-Coupling between Haloalkane and Aryl Grignard Reagent Catalyzed by Iron-SciOPP Complexes
por: Sharma, Akhilesh K., et al.
Publicado: (2020)

Thioesters as Acyl Donors in Biocatalytic Friedel‐Crafts‐type Acylation Catalyzed by Acyltransferase from Pseudomonas Protegens
por: Żądło‐Dobrowolska, Anna, et al.
Publicado: (2019)

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides
por: Luo, Jie, et al.
Publicado: (2020)

Copper-catalyzed arylation of alkyl halides with arylaluminum reagents
por: Shrestha, Bijay, et al.
Publicado: (2015)

Polythioesters Prepared by Ring‐Opening Polymerization of Cyclic Thioesters and Related Monomers
por: Li, Hui, et al.
Publicado: (2022)

Grignard Reagent-Catalyzed Hydroboration of Esters, Nitriles, and Imines
por: Han, Hyun Ji, et al.
Publicado: (2023)

Nickel-catalyzed coupling reaction of alkyl halides with aryl Grignard reagents in the presence of 1,3-butadiene: mechanistic studies of four-component coupling and competing cross-coupling reactions
por: Iwasaki, Takanori, et al.
Publicado: (2018)

Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagent
por: Wang, Xiao-Ping, et al.
Publicado: (2013)

Copper-catalyzed aminoalkynylation of alkenes with hypervalent iodine reagents
por: Shen, Kun, et al.
Publicado: (2017)

Mechanistic Studies of the TRIP-Catalyzed Allylation with Organozinc Reagents
por: Hartmann, Peter E., et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_oam2dn1mpvk464sumoi0lqfatq