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Towards Solving the PFAS Problem: The Potential Role of Metal‐Organic Frameworks

Per‐ and polyfluoroalkyl substances (PFAS) are a group of recalcitrant molecules that have been used since the 1940s in a variety of applications. They are now linked to a host of negative health outcomes and are extremely resistant to degradation under environmental conditions. Currently, membrane...

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Autores principales: FitzGerald, Laura I., Olorunyomi, Joseph F., Singh, Ruhani, Doherty, Cara M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804497/
https://www.ncbi.nlm.nih.gov/pubmed/35843909
http://dx.doi.org/10.1002/cssc.202201136
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author FitzGerald, Laura I.
Olorunyomi, Joseph F.
Singh, Ruhani
Doherty, Cara M.
author_facet FitzGerald, Laura I.
Olorunyomi, Joseph F.
Singh, Ruhani
Doherty, Cara M.
author_sort FitzGerald, Laura I.
collection PubMed
description Per‐ and polyfluoroalkyl substances (PFAS) are a group of recalcitrant molecules that have been used since the 1940s in a variety of applications. They are now linked to a host of negative health outcomes and are extremely resistant to degradation under environmental conditions. Currently, membrane technologies or adsorbents are used to remediate contaminated water. These techniques are either inefficient at capturing smaller PFAS molecules, have high energy demands, or result in concentrated waste that must be incinerated at high temperatures. This Review focuses on what role metal‐organic frameworks (MOFs) may play in addressing the PFAS problem. Specifically, how the unique properties of MOFs such as their well‐defined pore sizes, ultra‐high internal surface area, and tunable surface chemistry may be a sustainable solution for PFAS contamination.
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spelling pubmed-98044972023-01-03 Towards Solving the PFAS Problem: The Potential Role of Metal‐Organic Frameworks FitzGerald, Laura I. Olorunyomi, Joseph F. Singh, Ruhani Doherty, Cara M. ChemSusChem Reviews Per‐ and polyfluoroalkyl substances (PFAS) are a group of recalcitrant molecules that have been used since the 1940s in a variety of applications. They are now linked to a host of negative health outcomes and are extremely resistant to degradation under environmental conditions. Currently, membrane technologies or adsorbents are used to remediate contaminated water. These techniques are either inefficient at capturing smaller PFAS molecules, have high energy demands, or result in concentrated waste that must be incinerated at high temperatures. This Review focuses on what role metal‐organic frameworks (MOFs) may play in addressing the PFAS problem. Specifically, how the unique properties of MOFs such as their well‐defined pore sizes, ultra‐high internal surface area, and tunable surface chemistry may be a sustainable solution for PFAS contamination. John Wiley and Sons Inc. 2022-08-04 2022-10-10 /pmc/articles/PMC9804497/ /pubmed/35843909 http://dx.doi.org/10.1002/cssc.202201136 Text en © 2022 Commonwealth of Australia. ChemSusChem published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ (https://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Reviews
FitzGerald, Laura I.
Olorunyomi, Joseph F.
Singh, Ruhani
Doherty, Cara M.
Towards Solving the PFAS Problem: The Potential Role of Metal‐Organic Frameworks
title Towards Solving the PFAS Problem: The Potential Role of Metal‐Organic Frameworks
title_full Towards Solving the PFAS Problem: The Potential Role of Metal‐Organic Frameworks
title_fullStr Towards Solving the PFAS Problem: The Potential Role of Metal‐Organic Frameworks
title_full_unstemmed Towards Solving the PFAS Problem: The Potential Role of Metal‐Organic Frameworks
title_short Towards Solving the PFAS Problem: The Potential Role of Metal‐Organic Frameworks
title_sort towards solving the pfas problem: the potential role of metal‐organic frameworks
topic Reviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804497/
https://www.ncbi.nlm.nih.gov/pubmed/35843909
http://dx.doi.org/10.1002/cssc.202201136
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