Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry

Increasing the metal‐to‐ligand charge transfer (MLCT) excited state lifetime of polypyridine iron(II) complexes can be achieved by lowering the ligand's π* orbital energy and by increasing the ligand field splitting. In the homo‐ and heteroleptic complexes [Fe(cpmp)(2)](2+) (1(2+) ) and [Fe(cpm...

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Detalles Bibliográficos
Autores principales: Moll, Johannes, Naumann, Robert, Sorge, Lukas, Förster, Christoph, Gessner, Niklas, Burkhardt, Lukas, Ugur, Naz, Nuernberger, Patrick, Seidel, Wolfram, Ramanan, Charusheela, Bauer, Matthias, Heinze, Katja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804653/
https://www.ncbi.nlm.nih.gov/pubmed/35862259
http://dx.doi.org/10.1002/chem.202201858

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804653/
https://www.ncbi.nlm.nih.gov/pubmed/35862259
http://dx.doi.org/10.1002/chem.202201858

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