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Revisiting Formal Copper(III) Complexes: Bridging Perspectives with Quasi‐d ( 10 ) Configurations

The formal Cu(III) complex [Cu(CF(3))(4)](1−) has often served as a paradigmatic example of challenging oxidation state assignment – with many reports proposing conflicting descriptions. Here we report a computational analysis of this compound, employing Energy Decomposition Analysis and Intrinsic B...

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Detalles Bibliográficos
Autores principales: Leach, Isaac F., Havenith, Remco W. A., Klein, Johannes E. M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804752/
https://www.ncbi.nlm.nih.gov/pubmed/36619312
http://dx.doi.org/10.1002/ejic.202200247