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Boosting the Enantioselectivity of Conjugate Borylation of α,β‐Disubstituted Cyclobutenones with Monooxides of Chiral C (2)‐Symmetric Bis(phosphine) Ligands

Chiral bis(phosphine) monooxides (BPMOs) derived from C (2)‐symmetric bis(phosphines) have been found to induce superior levels of enantioselection in copper‐catalyzed conjugate borylation of α,β‐disubstituted cyclobutenones. More precisely, enantiomeric excesses as well as chemical yields are excee...

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Detalles Bibliográficos
Autores principales: Cui, Ming, Zhao, Zhi‐Yuan, Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804767/
https://www.ncbi.nlm.nih.gov/pubmed/35816363
http://dx.doi.org/10.1002/chem.202202163