Unravelling the Mechanistic Pathway of the Hydrogen Evolution Reaction Driven by a Cobalt Catalyst

A cobalt complex bearing a κ‐N(3)P(2) ligand is presented (1 (+) or Co(I)(L), where L is (1E,1′E)‐1,1′‐(pyridine‐2,6‐diyl)bis(N‐(3‐(diphenylphosphanyl)propyl)ethan‐1‐imine). Complex 1 (+) is stable under air at oxidation state Co(I) thanks to the π‐acceptor character of the phosphine groups. Electro...

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Detalles Bibliográficos
Autores principales: Jiang, Bing, Gil‐Sepulcre, Marcos, Garrido‐Barros, Pablo, Gimbert‐Suriñach, Carolina, Wang, Jia‐Wei, Garcia‐Anton, Jordi, Nolis, Pau, Benet‐Buchholz, Jordi, Romero, Nuria, Sala, Xavier, Llobet, Antoni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804897/
https://www.ncbi.nlm.nih.gov/pubmed/35922381
http://dx.doi.org/10.1002/anie.202209075

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804897/
https://www.ncbi.nlm.nih.gov/pubmed/35922381
http://dx.doi.org/10.1002/anie.202209075

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