Cargando…

Unravelling the Mechanistic Pathway of the Hydrogen Evolution Reaction Driven by a Cobalt Catalyst

A cobalt complex bearing a κ‐N(3)P(2) ligand is presented (1 (+) or Co(I)(L), where L is (1E,1′E)‐1,1′‐(pyridine‐2,6‐diyl)bis(N‐(3‐(diphenylphosphanyl)propyl)ethan‐1‐imine). Complex 1 (+) is stable under air at oxidation state Co(I) thanks to the π‐acceptor character of the phosphine groups. Electro...

Descripción completa

Detalles Bibliográficos
Autores principales:	Jiang, Bing, Gil‐Sepulcre, Marcos, Garrido‐Barros, Pablo, Gimbert‐Suriñach, Carolina, Wang, Jia‐Wei, Garcia‐Anton, Jordi, Nolis, Pau, Benet‐Buchholz, Jordi, Romero, Nuria, Sala, Xavier, Llobet, Antoni
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804897/ https://www.ncbi.nlm.nih.gov/pubmed/35922381 http://dx.doi.org/10.1002/anie.202209075

Ejemplares similares

Analysis of the Active Species Responsible for Water Oxidation Using a Pentanuclear Fe Complex
por: Pelosin, Primavera, et al.
Publicado: (2020)

Electrocatalytic water oxidation from a mixed linker MOF based on NU-1000 with an integrated ruthenium-based metallo-linker
por: Howe, Andrew, et al.
Publicado: (2022)

Interplay between β-Diimino and β-Diketiminato Ligands in Nickel Complexes Active in the Proton Reduction Reaction
por: Jameei Moghaddam, Navid, et al.
Publicado: (2022)

Consecutive Ligand‐Based Electron Transfer in New Molecular Copper‐Based Water Oxidation Catalysts
por: Gil‐Sepulcre, Marcos, et al.
Publicado: (2021)

Synthetic strategies to incorporate Ru-terpyridyl water oxidation catalysts into MOFs: direct synthesis vs. post-synthetic approach†
por: Liseev, Timofey, et al.
Publicado: (2020)

Synthesis, structure, spectroscopy and reactivity of new heterotrinuclear water oxidation catalysts
por: Mognon, Lorenzo, et al.
Publicado: (2016)

A cobalt phosphide catalyst for the hydrogenation of nitriles
por: Mitsudome, Takato, et al.
Publicado: (2020)

Recent Developments in Hydrogen Evolving Molecular Cobalt(II)-Polypyridyl Catalysts
por: Queyriaux, N., et al.
Publicado: (2015)

Silica accelerates the selective hydrogenation of CO(2) to methanol on cobalt catalysts
por: Wang, Lingxiang, et al.
Publicado: (2020)

Supported cobalt catalysts for the selective hydrogenation of ethyl levulinate to various chemicals
por: Cen, Youliang, et al.
Publicado: (2018)

Ligand-enabled and magnesium-activated hydrogenation with earth-abundant cobalt catalysts
por: Han, Bo, et al.
Publicado: (2021)

An efficient molybdenum disulfide/cobalt diselenide hybrid catalyst for electrochemical hydrogen generation
por: Gao, Min-Rui, et al.
Publicado: (2015)

Electrocatalytic hydrogenation of quinolines with water over a fluorine-modified cobalt catalyst
por: Guo, Shuoshuo, et al.
Publicado: (2022)

Mechanistic Complexity of Asymmetric Transfer Hydrogenation with Simple Mn–Diamine Catalysts
por: van Putten, Robbert, et al.
Publicado: (2019)

Constrained Parameter Estimation for a Mechanistic Kinetic Model of Cobalt–Hydrogen Electrochemical Competition during a Cobalt Removal Process
por: Liang, Yiting, et al.
Publicado: (2021)

Unravelling Enzymatic Features in a Supramolecular Iridium Catalyst by Computational Calculations
por: Tomasini, Michele, et al.
Publicado: (2022)

Air-stable 18-electron adducts of Schrock catalysts with tuned stability constants for spontaneous release of the active species
por: Gulyás, Henrik, et al.
Publicado: (2021)

Pendant Hydrogen-Bond Donors in Cobalt Catalysts Independently Enhance CO(2) Reduction
por: Chapovetsky, Alon, et al.
Publicado: (2018)

Cobalt-based nanoparticles prepared from MOF–carbon templates as efficient hydrogenation catalysts
por: Murugesan, Kathiravan, et al.
Publicado: (2018)

Hydrogenation of terminal and internal olefins using a biowaste-derived heterogeneous cobalt catalyst
por: Scharnagl, Florian Korbinian, et al.
Publicado: (2018)

Origin of synergistic effects in bicomponent cobalt oxide-platinum catalysts for selective hydrogenation reaction
por: Zhang, Jiankang, et al.
Publicado: (2019)

Author Correction: Silica accelerates the selective hydrogenation of CO(2) to methanol on cobalt catalysts
por: Wang, Lingxiang, et al.
Publicado: (2020)

Impacts of Metal–Support Interaction on Hydrogen Evolution Reaction of Cobalt-Nitride-Carbide Catalyst
por: Zhang, Xuan, et al.
Publicado: (2022)

Phase-Controlled Cobalt Catalyst Boosting Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran
por: Yang, Kaixuan, et al.
Publicado: (2023)

Tuning and mechanistic insights of metal chalcogenide molecular catalysts for the hydrogen-evolution reaction
por: McAllister, James, et al.
Publicado: (2019)

Mechanistic Insight Into the Application of Alumina-Supported Pd Catalysts for the Hydrogenation of Nitrobenzene to Aniline
por: Morisse, Clément G. A., et al.
Publicado: (2022)

Metabolomic fingerprinting of pig seminal plasma identifies in vivo fertility biomarkers
por: Mateo-Otero, Yentel, et al.
Publicado: (2021)

Unraveling surface structures of gallium promoted transition metal catalysts in CO(2) hydrogenation
por: Lee, Si Woo, et al.
Publicado: (2023)

A highly active and stable hydrogen evolution catalyst based on pyrite-structured cobalt phosphosulfide
por: Liu, Wen, et al.
Publicado: (2016)

The hydrogenation of mandelonitrile over a Pd/C catalyst: towards a mechanistic understanding
por: McAllister, Mairi I., et al.
Publicado: (2019)

Unraveling the Nature of Sites Active toward Hydrogen Peroxide Reduction in Fe‐N‐C Catalysts
por: Choi, Chang Hyuck, et al.
Publicado: (2017)

A General Catalyst Based on Cobalt Core–Shell Nanoparticles for the Hydrogenation of N‐Heteroarenes Including Pyridines
por: Murugesan, Kathiravan, et al.
Publicado: (2020)

Selective and Additive‐Free Hydrogenation of Nitroarenes Mediated by a DMSO‐Tagged Molecular Cobalt Corrole Catalyst
por: Timelthaler, Daniel, et al.
Publicado: (2021)

Access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction
por: Ahmed, Imtiaz, et al.
Publicado: (2023)

Amine Functionalization Leads to Enhanced Performance for Nickel- and Cobalt-Ferrite-Supported Palladium Catalysts in Nitrobenzene Hydrogenation
por: Hajdu, Viktória, et al.
Publicado: (2023)

trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
por: Redford, Christopher, et al.
Publicado: (2012)

A dimer of bis(N-heterocyclic carbene)rhodium(I) centres spanned by a dibenzo-18-crown-6 bridge from synchrotron radiation
por: Shrestha, Sumi, et al.
Publicado: (2012)

Cobalt-based Catalysts for Ammonia Decomposition
por: Lendzion-Bielun, Zofia, et al.
Publicado: (2013)

Recyclable Mn(I) Catalysts for Base‐Free Asymmetric Hydrogenation: Mechanistic, DFT and Catalytic Studies
por: Jayaprakash, Harikrishnan, et al.
Publicado: (2022)

Nanostructure of nickel-promoted indium oxide catalysts drives selectivity in CO(2) hydrogenation
por: Frei, Matthias S., et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_fgs5ba7oed21pm79h0ua14aj53