Molybdenum(VI) Bis(imido) Complexes: From Frustrated Lewis Pairs to Weakly Coordinating Cations

Molybdenum(VI) bis(imido) complexes [Mo(NtBu)(2)(L(R))(2)] (R=H 1 a; R=CF(3) 1 b) combined with B(C(6)F(5))(3) (1 a/B(C(6)F(5))(3), 1 b/B(C(6)F(5))(3)) exhibit a frustrated Lewis pair (FLP) character that can heterolytically split H−H, Si−H and O−H bonds. Cleavage of H(2) and Et(3)SiH affords ion pa...

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Detalles Bibliográficos
Autores principales: Milinkovic, Angela, Dupé, Antoine, Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805034/
https://www.ncbi.nlm.nih.gov/pubmed/35775999
http://dx.doi.org/10.1002/chem.202201867

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805034/
https://www.ncbi.nlm.nih.gov/pubmed/35775999
http://dx.doi.org/10.1002/chem.202201867

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