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Molybdenum(VI) Bis(imido) Complexes: From Frustrated Lewis Pairs to Weakly Coordinating Cations
Molybdenum(VI) bis(imido) complexes [Mo(NtBu)(2)(L(R))(2)] (R=H 1 a; R=CF(3) 1 b) combined with B(C(6)F(5))(3) (1 a/B(C(6)F(5))(3), 1 b/B(C(6)F(5))(3)) exhibit a frustrated Lewis pair (FLP) character that can heterolytically split H−H, Si−H and O−H bonds. Cleavage of H(2) and Et(3)SiH affords ion pa...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805034/ https://www.ncbi.nlm.nih.gov/pubmed/35775999 http://dx.doi.org/10.1002/chem.202201867 |