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Synthesis of a Hexachloro Sulfate(IV) Dianion Enabled by Polychloride Chemistry

The preparation and structural characterization of [NEt(3)Me](2)[SCl(6)] is described, which is the first example of a [SCl(6)](2−) dianion and of a halosulfate anion of the type [S( x )X( y )]( z−) in general. This dianion belongs to the group of 14‐valence electron AB(6)E systems and forms an octa...

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Detalles Bibliográficos
Autores principales:	Voßnacker, Patrick, Wüst, Alisa, Müller, Carsten, Kleoff, Merlin, Riedel, Sebastian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805220/ https://www.ncbi.nlm.nih.gov/pubmed/35924885 http://dx.doi.org/10.1002/anie.202209684

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