Cargando…
Racemic Total Synthesis of Elmonin and Pratenone A, from Streptomyces, Using a Common Intermediate Prepared by peri-Directed C–H Functionalization
[Image: see text] The first total synthesis of elmonin and pratenone A, two complex rearranged angucyclinones from Streptomyces, is reported. Using peri-directed C–H functionalization, the key naphthalene fragment present in both synthetic targets was efficiently prepared. Coupling to two anisole-de...
Autores principales: | Uiterweerd, Michiel T., Minnaard, Adriaan J. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9806855/ https://www.ncbi.nlm.nih.gov/pubmed/36533980 http://dx.doi.org/10.1021/acs.orglett.2c03449 |
Ejemplares similares
-
Enantioselective terpolymerization of racemic and meso-epoxides with anhydrides for preparation of chiral polyesters
por: Li, Jie, et al.
Publicado: (2020) -
Efficient resolution of racemic crown-shaped cyclotriveratrylene derivatives and isolation and characterization of the intermediate saddle isomer
por: Götz, Sven, et al.
Publicado: (2019) -
In-peptide amino acid racemization via inter-residue oxazoline intermediates during acidic hydrolysis
por: Broberg, Anders, et al.
Publicado: (2021) -
Asymmetric total synthesis of a putative sex pheromone component from the parasitoid wasp Trichogramma turkestanica
por: Geerdink, Danny, et al.
Publicado: (2014) -
Production of Atosiban’s Key Intermediate Pentapeptide: Synthetic Approaches to the Development of a Peptide Synthesis with Less Racemization and Simplifier Purification Process
por: Ma, Chunying, et al.
Publicado: (2022)