Ligand‐Promoted [Pd]‐Catalyzed α‐Alkylation of Ketones through a Borrowing‐Hydrogen Approach

A new class of palladium complexes bearing bidentate 2‐hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal‐ligand cooperative borrowing‐hydrogen (BH) process were demonstra...

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Detalles Bibliográficos
Autores principales: Manojveer, Seetharaman, Garg, Nitish K., Gul, Zarif, Kanwal, Ayesha, Goriya, Yogesh, Johnson, Magnus T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9807026/
https://www.ncbi.nlm.nih.gov/pubmed/36592045
http://dx.doi.org/10.1002/open.202200245
Descripción
Sumario:A new class of palladium complexes bearing bidentate 2‐hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal‐ligand cooperative borrowing‐hydrogen (BH) process were demonstrated.

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