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A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst

In this study, cobalt composite immobilized on polysulfone fibrous network nanoparticles (CCPSF NPs) were synthesized in a controllable and one-step way under microwave-assisted conditions. The structure of CCPSF NPs was characterized by SEM images (for morphology and size distribution), TGA (for th...

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Autores principales: Ramírez-Coronel, Andrés Alexis, Mezan, Salim Oudah, Patra, Indrajit, Sivaraman, Ramaswamy, Riadi, Yassine, Khakberdiev, Shukhrat, Lafta, Holya A., Abosaooda, Munther, Turki Jalil, Abduladheem, Fakri Mustafa, Yasser
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9807923/
https://www.ncbi.nlm.nih.gov/pubmed/36605117
http://dx.doi.org/10.3389/fchem.2022.1015515
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author Ramírez-Coronel, Andrés Alexis
Mezan, Salim Oudah
Patra, Indrajit
Sivaraman, Ramaswamy
Riadi, Yassine
Khakberdiev, Shukhrat
Lafta, Holya A.
Abosaooda, Munther
Turki Jalil, Abduladheem
Fakri Mustafa, Yasser
author_facet Ramírez-Coronel, Andrés Alexis
Mezan, Salim Oudah
Patra, Indrajit
Sivaraman, Ramaswamy
Riadi, Yassine
Khakberdiev, Shukhrat
Lafta, Holya A.
Abosaooda, Munther
Turki Jalil, Abduladheem
Fakri Mustafa, Yasser
author_sort Ramírez-Coronel, Andrés Alexis
collection PubMed
description In this study, cobalt composite immobilized on polysulfone fibrous network nanoparticles (CCPSF NPs) were synthesized in a controllable and one-step way under microwave-assisted conditions. The structure of CCPSF NPs was characterized by SEM images (for morphology and size distribution), TGA (for thermal stability), BET technique (for the specific surface area), FT-IR spectroscopy (for relation group characterization), and XRD patterns (for crystal size). The oxidation of the primary and secondary alcohols to aldehyde and ketone was investigated using synthesized CCPSF NPs under solvent-free microwave-assisted conditions, and high oxidizing activity was observed. In addition to oxidation properties, the anticancer activity of the synthesized CCPSF NPs in breast cancer was evaluated by the MTT method , and significant results were obtained.
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spelling pubmed-98079232023-01-04 A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst Ramírez-Coronel, Andrés Alexis Mezan, Salim Oudah Patra, Indrajit Sivaraman, Ramaswamy Riadi, Yassine Khakberdiev, Shukhrat Lafta, Holya A. Abosaooda, Munther Turki Jalil, Abduladheem Fakri Mustafa, Yasser Front Chem Chemistry In this study, cobalt composite immobilized on polysulfone fibrous network nanoparticles (CCPSF NPs) were synthesized in a controllable and one-step way under microwave-assisted conditions. The structure of CCPSF NPs was characterized by SEM images (for morphology and size distribution), TGA (for thermal stability), BET technique (for the specific surface area), FT-IR spectroscopy (for relation group characterization), and XRD patterns (for crystal size). The oxidation of the primary and secondary alcohols to aldehyde and ketone was investigated using synthesized CCPSF NPs under solvent-free microwave-assisted conditions, and high oxidizing activity was observed. In addition to oxidation properties, the anticancer activity of the synthesized CCPSF NPs in breast cancer was evaluated by the MTT method , and significant results were obtained. Frontiers Media S.A. 2022-12-20 /pmc/articles/PMC9807923/ /pubmed/36605117 http://dx.doi.org/10.3389/fchem.2022.1015515 Text en Copyright © 2022 Ramírez-Coronel, Mezan, Patra, Sivaraman, Riadi, Khakberdiev, Lafta, Abosaooda, Turki Jalil and Fakri Mustafa. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Ramírez-Coronel, Andrés Alexis
Mezan, Salim Oudah
Patra, Indrajit
Sivaraman, Ramaswamy
Riadi, Yassine
Khakberdiev, Shukhrat
Lafta, Holya A.
Abosaooda, Munther
Turki Jalil, Abduladheem
Fakri Mustafa, Yasser
A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst
title A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst
title_full A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst
title_fullStr A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst
title_full_unstemmed A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst
title_short A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst
title_sort green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9807923/
https://www.ncbi.nlm.nih.gov/pubmed/36605117
http://dx.doi.org/10.3389/fchem.2022.1015515
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