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Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis

Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science, medicinal chemistry, and future industrial applications in energy storage and conversion. To date, there has not been a detailed review on electro‐organic synthesis with the strategy of heterogeneous catalysis. In...

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Autores principales: Ali, Tariq, Wang, Haiyan, Iqbal, Waseem, Bashir, Tariq, Shah, Rahim, Hu, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811472/
https://www.ncbi.nlm.nih.gov/pubmed/36398622
http://dx.doi.org/10.1002/advs.202205077
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author Ali, Tariq
Wang, Haiyan
Iqbal, Waseem
Bashir, Tariq
Shah, Rahim
Hu, Yong
author_facet Ali, Tariq
Wang, Haiyan
Iqbal, Waseem
Bashir, Tariq
Shah, Rahim
Hu, Yong
author_sort Ali, Tariq
collection PubMed
description Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science, medicinal chemistry, and future industrial applications in energy storage and conversion. To date, there has not been a detailed review on electro‐organic synthesis with the strategy of heterogeneous catalysis. In this review, the most recent advances in synthesizing value‐added chemicals by heterogeneous catalysis are summarized. An overview of electrocatalytic oxidation and reduction processes as well as paired electrocatalysis is provided, and the anodic oxidation of alcohols (monohydric and polyhydric), aldehydes, and amines are discussed. This review also provides in‐depth insight into the cathodic reduction of carboxylates, carbon dioxide, C=C, C≡C, and reductive coupling reactions. Moreover, the electrocatalytic paired electro‐synthesis methods, including parallel paired, sequential divergent paired, and convergent paired electrolysis, are summarized. Additionally, the strategies developed to achieve high electrosynthesis efficiency and the associated challenges are also addressed. It is believed that electro‐organic synthesis is a promising direction of organic electrochemistry, offering numerous opportunities to develop new organic reaction methods.
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spelling pubmed-98114722023-01-05 Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis Ali, Tariq Wang, Haiyan Iqbal, Waseem Bashir, Tariq Shah, Rahim Hu, Yong Adv Sci (Weinh) Reviews Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science, medicinal chemistry, and future industrial applications in energy storage and conversion. To date, there has not been a detailed review on electro‐organic synthesis with the strategy of heterogeneous catalysis. In this review, the most recent advances in synthesizing value‐added chemicals by heterogeneous catalysis are summarized. An overview of electrocatalytic oxidation and reduction processes as well as paired electrocatalysis is provided, and the anodic oxidation of alcohols (monohydric and polyhydric), aldehydes, and amines are discussed. This review also provides in‐depth insight into the cathodic reduction of carboxylates, carbon dioxide, C=C, C≡C, and reductive coupling reactions. Moreover, the electrocatalytic paired electro‐synthesis methods, including parallel paired, sequential divergent paired, and convergent paired electrolysis, are summarized. Additionally, the strategies developed to achieve high electrosynthesis efficiency and the associated challenges are also addressed. It is believed that electro‐organic synthesis is a promising direction of organic electrochemistry, offering numerous opportunities to develop new organic reaction methods. John Wiley and Sons Inc. 2022-11-18 /pmc/articles/PMC9811472/ /pubmed/36398622 http://dx.doi.org/10.1002/advs.202205077 Text en © 2022 The Authors. Advanced Science published by Wiley‐VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Reviews
Ali, Tariq
Wang, Haiyan
Iqbal, Waseem
Bashir, Tariq
Shah, Rahim
Hu, Yong
Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis
title Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis
title_full Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis
title_fullStr Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis
title_full_unstemmed Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis
title_short Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis
title_sort electro‐synthesis of organic compounds with heterogeneous catalysis
topic Reviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811472/
https://www.ncbi.nlm.nih.gov/pubmed/36398622
http://dx.doi.org/10.1002/advs.202205077
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