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Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis
Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science, medicinal chemistry, and future industrial applications in energy storage and conversion. To date, there has not been a detailed review on electro‐organic synthesis with the strategy of heterogeneous catalysis. In...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811472/ https://www.ncbi.nlm.nih.gov/pubmed/36398622 http://dx.doi.org/10.1002/advs.202205077 |
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author | Ali, Tariq Wang, Haiyan Iqbal, Waseem Bashir, Tariq Shah, Rahim Hu, Yong |
author_facet | Ali, Tariq Wang, Haiyan Iqbal, Waseem Bashir, Tariq Shah, Rahim Hu, Yong |
author_sort | Ali, Tariq |
collection | PubMed |
description | Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science, medicinal chemistry, and future industrial applications in energy storage and conversion. To date, there has not been a detailed review on electro‐organic synthesis with the strategy of heterogeneous catalysis. In this review, the most recent advances in synthesizing value‐added chemicals by heterogeneous catalysis are summarized. An overview of electrocatalytic oxidation and reduction processes as well as paired electrocatalysis is provided, and the anodic oxidation of alcohols (monohydric and polyhydric), aldehydes, and amines are discussed. This review also provides in‐depth insight into the cathodic reduction of carboxylates, carbon dioxide, C=C, C≡C, and reductive coupling reactions. Moreover, the electrocatalytic paired electro‐synthesis methods, including parallel paired, sequential divergent paired, and convergent paired electrolysis, are summarized. Additionally, the strategies developed to achieve high electrosynthesis efficiency and the associated challenges are also addressed. It is believed that electro‐organic synthesis is a promising direction of organic electrochemistry, offering numerous opportunities to develop new organic reaction methods. |
format | Online Article Text |
id | pubmed-9811472 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-98114722023-01-05 Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis Ali, Tariq Wang, Haiyan Iqbal, Waseem Bashir, Tariq Shah, Rahim Hu, Yong Adv Sci (Weinh) Reviews Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science, medicinal chemistry, and future industrial applications in energy storage and conversion. To date, there has not been a detailed review on electro‐organic synthesis with the strategy of heterogeneous catalysis. In this review, the most recent advances in synthesizing value‐added chemicals by heterogeneous catalysis are summarized. An overview of electrocatalytic oxidation and reduction processes as well as paired electrocatalysis is provided, and the anodic oxidation of alcohols (monohydric and polyhydric), aldehydes, and amines are discussed. This review also provides in‐depth insight into the cathodic reduction of carboxylates, carbon dioxide, C=C, C≡C, and reductive coupling reactions. Moreover, the electrocatalytic paired electro‐synthesis methods, including parallel paired, sequential divergent paired, and convergent paired electrolysis, are summarized. Additionally, the strategies developed to achieve high electrosynthesis efficiency and the associated challenges are also addressed. It is believed that electro‐organic synthesis is a promising direction of organic electrochemistry, offering numerous opportunities to develop new organic reaction methods. John Wiley and Sons Inc. 2022-11-18 /pmc/articles/PMC9811472/ /pubmed/36398622 http://dx.doi.org/10.1002/advs.202205077 Text en © 2022 The Authors. Advanced Science published by Wiley‐VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Reviews Ali, Tariq Wang, Haiyan Iqbal, Waseem Bashir, Tariq Shah, Rahim Hu, Yong Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis |
title | Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis |
title_full | Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis |
title_fullStr | Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis |
title_full_unstemmed | Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis |
title_short | Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis |
title_sort | electro‐synthesis of organic compounds with heterogeneous catalysis |
topic | Reviews |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811472/ https://www.ncbi.nlm.nih.gov/pubmed/36398622 http://dx.doi.org/10.1002/advs.202205077 |
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