Cargando…

Photocatalytic enantioselective Minisci reaction of β-carbolines and application to natural product synthesis

A highly efficient enantioselective direct C–H functionalization of β-carbolines via a Minisci-type radical process under a photo-redox and chiral phosphoric acid cooperative catalytic system has been disclosed. Through this protocol, a wide range of C1 aminoalkylated β-carbolines were constructed d...

Descripción completa

Detalles Bibliográficos
Autores principales:	Luo, Mu-Peng, Gu, Yi-Jie, Wang, Shou-Guo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811569/ https://www.ncbi.nlm.nih.gov/pubmed/36687353 http://dx.doi.org/10.1039/d2sc05313f

Ejemplares similares

Discovery and Development of the Enantioselective Minisci Reaction
por: Bacoş, P. David, et al.
Publicado: (2023)

Hydrogen Atom Transfer-Driven Enantioselective Minisci Reaction of Amides
por: Proctor, Rupert S. J., et al.
Publicado: (2021)

Hydrogen Atom Transfer Driven Enantioselective Minisci Reaction of Alcohols
por: Colgan, Avene C., et al.
Publicado: (2022)

Photocatalytic Decarboxylative Minisci Reaction Catalyzed by Palladium-Loaded Gallium Nitride
por: Tan, Lida, et al.
Publicado: (2023)

Bifunctional thiosquaramide catalyzed asymmetric reduction of dihydro-β-carbolines and enantioselective synthesis of (−)-coerulescine and (−)-horsfiline by oxidative rearrangement
por: Sathish, Manda, et al.
Publicado: (2020)

Predictive Multivariate Linear Regression Analysis Guides Successful Catalytic Enantioselective Minisci Reactions of Diazines
por: Reid, Jolene P., et al.
Publicado: (2019)

Photo-redox catalyzed dehydrazinative acylation of N-heterocycles via Minisci reaction
por: Hafeez, Saira, et al.
Publicado: (2021)

A Computational and Experimental Investigation of the Origin of Selectivity in the Chiral Phosphoric Acid Catalyzed Enantioselective Minisci Reaction
por: Ermanis, Kristaps, et al.
Publicado: (2020)

Comprehensive review of α-carboline alkaloids: Natural products, updated synthesis, and biological activities
por: Li, Deping, et al.
Publicado: (2022)

Synthesis and characterization of new fluorescent boro-β-carboline dyes
por: Szepesi Kovács, Dénes, et al.
Publicado: (2021)

Synthesis of tetrahydro-β-carbolines from 2-indolylmethyl azides and propargylic alcohols
por: Yin, Haiting, et al.
Publicado: (2021)

General electrochemical Minisci alkylation of N-heteroarenes with alkyl halides
por: del Río-Rodríguez, Roberto, et al.
Publicado: (2022)

The Chiral Pool in the Pictet–Spengler Reaction for the Synthesis of β-Carbolines
por: Dalpozzo, Renato
Publicado: (2016)

Photoredox-mediated Minisci C–H alkylation of N-heteroarenes using boronic acids and hypervalent iodine
por: Li, Guo-Xing, et al.
Publicado: (2016)

Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions
por: Guo, Jun-Xia, et al.
Publicado: (2016)

Correction: Photoredox-mediated Minisci C–H alkylation of N-heteroarenes using boronic acids and hypervalent iodine
por: Li, Guo-Xing, et al.
Publicado: (2016)

Synthesis and Fungicidal Activity of β-Carboline Alkaloids and Their Derivatives
por: Li, Zhibin, et al.
Publicado: (2015)

A practical and sustainable two-component Minisci alkylation via photo-induced EDA-complex activation
por: Sharique, Mohammed, et al.
Publicado: (2022)

TCCA-mediated oxidative rearrangement of tetrahydro-β-carbolines: facile access to spirooxindoles and the total synthesis of (±)-coerulescine and (±)-horsfiline
por: Sathish, Manda, et al.
Publicado: (2021)

A Visible Light-Driven Minisci-Type Reaction with N-Hydroxyphthalimide Esters
por: Kammer, Lisa Marie, et al.
Publicado: (2018)

Recent Advances in the Synthesis of β-Carboline Alkaloids
por: Szabó, Tímea, et al.
Publicado: (2021)

Catalytic enantioselective intramolecular Tishchenko reaction of meso-dialdehyde: synthesis of (S)-cedarmycins
por: Ismiyarto,, et al.
Publicado: (2021)

Enantioselective synthesis of quaternary 3,4-dihydroisoquinolinones via Heck carbonylation reactions: development and application to the synthesis of Minalrestat analogues
por: Cheng, Cang, et al.
Publicado: (2019)

Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones
por: Wang, De, et al.
Publicado: (2015)

Direct Assembly of Prenylated Heteroarenes through a Cascade Minisci Reaction/Dehydration Sequence
por: Tan, Dong‐Hang, et al.
Publicado: (2016)

Visible-light-mediated Minisci C–H alkylation of heteroarenes with unactivated alkyl halides using O(2) as an oxidant
por: Dong, Jianyang, et al.
Publicado: (2018)

Enantioselective synthesis of (–)-chloramphenicol via silver-catalysed asymmetric isocyanoacetate aldol reaction
por: Franchino, Allegra, et al.
Publicado: (2015)

Synthesis of β-Carbolines with Electrocyclic Cyclization of 3-Nitrovinylindoles
por: Aksenov, Nicolai A., et al.
Publicado: (2023)

Electrochemical oxidative rearrangement of tetrahydro-β-carbolines in a zero-gap flow cell
por: Zheng, Yiting, et al.
Publicado: (2022)

Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system
por: Huang, Xiaoqiang, et al.
Publicado: (2017)

Design and Synthesis of Fluorescent 1,3-Diaryl-β-carbolines and 1,3-Diaryl-3,4-dihydro-β-carbolines
por: Pu, JiYang, et al.
Publicado: (2021)

Correction: Visible-light-mediated Minisci C–H alkylation of heteroarenes with unactivated alkyl halides using O(2) as an oxidant
por: Dong, Jianyang, et al.
Publicado: (2022)

Diastereoselective approach to rationally design tetrahydro-β-carboline–isatin conjugates as potential SERMs against breast cancer
por: Sharma, Bharvi, et al.
Publicado: (2019)

Base-promoted cascade β-F-elimination/electrocyclization/Diels–Alder/retro-Diels–Alder reaction: efficient access to δ-carboline derivatives
por: Sun, Xi-Shang, et al.
Publicado: (2022)

Enantioselective synthesis of amines by combining photoredox and enzymatic catalysis in a cyclic reaction network
por: Guo, Xingwei, et al.
Publicado: (2018)

Novel base-initiated cascade reactions of hemiindigos to produce dipolar γ-carbolines and indole-fused pentacycles
por: Velezheva, V. S., et al.
Publicado: (2019)

Chiral bifunctional organocatalysts for enantioselective synthesis of 3-substituted isoindolinones
por: Hu, Xiao-Mu, et al.
Publicado: (2023)

Structure elucidation of nigricanoside A through enantioselective total synthesis
por: Chen, Jie, et al.
Publicado: (2015)

A bifunctional iminophosphorane squaramide catalyzed enantioselective synthesis of hydroquinazolines via intramolecular aza-Michael reaction to α,β-unsaturated esters
por: Su, Guanglong, et al.
Publicado: (2021)

Iminium and enamine catalysis in enantioselective photochemical reactions
por: Zou, You-Quan, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_jb9gbsp798e92klbj9nr2ssa7s