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Placing gold on a π(+)-surface: ligand design and impact on reactivity
We describe a novel gold chloride complex supported by an ambiphilic phosphine/xanthylium ligand in which the AuCl moiety interacts with the π(+) surface of the xanthylium unit as indicated by structural studies. Energy decomposition analyses carried out on a model system indicates the prevalence of...
Autores principales: | Liu, Wei-Chun, Gabbaï, François P. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811580/ https://www.ncbi.nlm.nih.gov/pubmed/36687358 http://dx.doi.org/10.1039/d2sc05574k |
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