Conversion of triphenylphosphine oxide to organophosphorus via selective cleavage of C-P, O-P, and C-H bonds with sodium

For over half a century, thousands of tons of triphenylphosphine oxide Ph(3)P(O) have been produced every year from the chemical industries as a useless chemical waste. Here we disclose efficient transformations of Ph(3)P(O) with cheap resource-abundant metallic sodium finely dispersed in paraffin o...

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Detalles Bibliográficos
Autores principales: Zhang, Jian-Qiu, Ye, Jingjing, Huang, Tianzeng, Shinohara, Hiroyuki, Fujino, Hiroyoshi, Han, Li-Biao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9812262/
https://www.ncbi.nlm.nih.gov/pubmed/36703346
http://dx.doi.org/10.1038/s42004-019-0249-6

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