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Magnetically separable triazine-based Cu(ii)–vitamin B(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides

In the current study, a highly efficient heterogeneous copper catalyst has been developed by supporting copper acetate on a magnetically separable triazine–vitamin B(5) system. After the successful characterization of the prepared nanoparticles by various techniques such as FT-IR, FE-SEM, EDX/MAP, X...

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Detalles Bibliográficos
Autores principales: Karimi, Farzaneh, Jadidi Nejad, Masoumeh, Salamatmanesh, Arefe, Heydari, Akbar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9813807/
https://www.ncbi.nlm.nih.gov/pubmed/36686960
http://dx.doi.org/10.1039/d2ra06104j
Descripción
Sumario:In the current study, a highly efficient heterogeneous copper catalyst has been developed by supporting copper acetate on a magnetically separable triazine–vitamin B(5) system. After the successful characterization of the prepared nanoparticles by various techniques such as FT-IR, FE-SEM, EDX/MAP, XRD, TEM, TGA, VSM, and ICP-OES, the catalytic efficiency of them were evaluated in the cyanation reaction of aryl halides in the presence of nitromethane as a non-toxic and cost-effective cyanation source. The cyanation products were obtained in desirable yields. Notably, the magnetic nanocatalyst can be easily recovered and reused at least five times without a significant decrease in its performance.