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Magnetically separable triazine-based Cu(ii)–vitamin B(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides
In the current study, a highly efficient heterogeneous copper catalyst has been developed by supporting copper acetate on a magnetically separable triazine–vitamin B(5) system. After the successful characterization of the prepared nanoparticles by various techniques such as FT-IR, FE-SEM, EDX/MAP, X...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9813807/ https://www.ncbi.nlm.nih.gov/pubmed/36686960 http://dx.doi.org/10.1039/d2ra06104j |
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author | Karimi, Farzaneh Jadidi Nejad, Masoumeh Salamatmanesh, Arefe Heydari, Akbar |
author_facet | Karimi, Farzaneh Jadidi Nejad, Masoumeh Salamatmanesh, Arefe Heydari, Akbar |
author_sort | Karimi, Farzaneh |
collection | PubMed |
description | In the current study, a highly efficient heterogeneous copper catalyst has been developed by supporting copper acetate on a magnetically separable triazine–vitamin B(5) system. After the successful characterization of the prepared nanoparticles by various techniques such as FT-IR, FE-SEM, EDX/MAP, XRD, TEM, TGA, VSM, and ICP-OES, the catalytic efficiency of them were evaluated in the cyanation reaction of aryl halides in the presence of nitromethane as a non-toxic and cost-effective cyanation source. The cyanation products were obtained in desirable yields. Notably, the magnetic nanocatalyst can be easily recovered and reused at least five times without a significant decrease in its performance. |
format | Online Article Text |
id | pubmed-9813807 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-98138072023-01-20 Magnetically separable triazine-based Cu(ii)–vitamin B(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides Karimi, Farzaneh Jadidi Nejad, Masoumeh Salamatmanesh, Arefe Heydari, Akbar RSC Adv Chemistry In the current study, a highly efficient heterogeneous copper catalyst has been developed by supporting copper acetate on a magnetically separable triazine–vitamin B(5) system. After the successful characterization of the prepared nanoparticles by various techniques such as FT-IR, FE-SEM, EDX/MAP, XRD, TEM, TGA, VSM, and ICP-OES, the catalytic efficiency of them were evaluated in the cyanation reaction of aryl halides in the presence of nitromethane as a non-toxic and cost-effective cyanation source. The cyanation products were obtained in desirable yields. Notably, the magnetic nanocatalyst can be easily recovered and reused at least five times without a significant decrease in its performance. The Royal Society of Chemistry 2023-01-05 /pmc/articles/PMC9813807/ /pubmed/36686960 http://dx.doi.org/10.1039/d2ra06104j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Karimi, Farzaneh Jadidi Nejad, Masoumeh Salamatmanesh, Arefe Heydari, Akbar Magnetically separable triazine-based Cu(ii)–vitamin B(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides |
title | Magnetically separable triazine-based Cu(ii)–vitamin B(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides |
title_full | Magnetically separable triazine-based Cu(ii)–vitamin B(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides |
title_fullStr | Magnetically separable triazine-based Cu(ii)–vitamin B(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides |
title_full_unstemmed | Magnetically separable triazine-based Cu(ii)–vitamin B(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides |
title_short | Magnetically separable triazine-based Cu(ii)–vitamin B(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides |
title_sort | magnetically separable triazine-based cu(ii)–vitamin b(5) complex in nitromethane toward efficient heterogeneous cyanation reaction of aryl halides |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9813807/ https://www.ncbi.nlm.nih.gov/pubmed/36686960 http://dx.doi.org/10.1039/d2ra06104j |
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