Open questions on bonding involving lanthanide atoms

In-depth understanding of the bonding characteristics of the lanthanide ions in contemporary lanthanide-based materials is mandatory for tailoring their properties for novel applications. Here, the authors elaborate on open questions regarding the bonding situation in mainly molecular lanthanide (4f...

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Detalles Bibliográficos
Autores principales: Vitova, T., Roesky, P. W., Dehnen, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Comment
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814189/
https://www.ncbi.nlm.nih.gov/pubmed/36697796
http://dx.doi.org/10.1038/s42004-022-00630-6
Descripción
Sumario:In-depth understanding of the bonding characteristics of the lanthanide ions in contemporary lanthanide-based materials is mandatory for tailoring their properties for novel applications. Here, the authors elaborate on open questions regarding the bonding situation in mainly molecular lanthanide (4f) compounds, where, as compared to their actinide (5f) analogs in which covalency of the bonds is a common feature, this is still under discussion for the 4f compounds.

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