Open questions in boron species with globally 4n π systems

The Hückel rule defines that monocyclic and planar conjugated systems containing [4n + 2] π electrons are aromatic. Here, the authors highlight boron species that feature a globally 4n π system, defying the Hückel rule, but nonetheless exhibit aromaticity.

Detalles Bibliográficos
Autores principales: Ota, Kei, Kinjo, Rei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Comment
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814197/
https://www.ncbi.nlm.nih.gov/pubmed/36697702
http://dx.doi.org/10.1038/s42004-021-00542-x
_version_ 1784864081515118592
author Ota, Kei
Kinjo, Rei
author_facet Ota, Kei
Kinjo, Rei
author_sort Ota, Kei
collection PubMed
description The Hückel rule defines that monocyclic and planar conjugated systems containing [4n + 2] π electrons are aromatic. Here, the authors highlight boron species that feature a globally 4n π system, defying the Hückel rule, but nonetheless exhibit aromaticity.
format Online
Article
Text
id pubmed-9814197
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher Nature Publishing Group UK
record_format MEDLINE/PubMed
spelling pubmed-98141972023-01-10 Open questions in boron species with globally 4n π systems Ota, Kei Kinjo, Rei Commun Chem Comment The Hückel rule defines that monocyclic and planar conjugated systems containing [4n + 2] π electrons are aromatic. Here, the authors highlight boron species that feature a globally 4n π system, defying the Hückel rule, but nonetheless exhibit aromaticity. Nature Publishing Group UK 2021-07-13 /pmc/articles/PMC9814197/ /pubmed/36697702 http://dx.doi.org/10.1038/s42004-021-00542-x Text en © The Author(s) 2021 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Comment
Ota, Kei
Kinjo, Rei
Open questions in boron species with globally 4n π systems
title Open questions in boron species with globally 4n π systems
title_full Open questions in boron species with globally 4n π systems
title_fullStr Open questions in boron species with globally 4n π systems
title_full_unstemmed Open questions in boron species with globally 4n π systems
title_short Open questions in boron species with globally 4n π systems
title_sort open questions in boron species with globally 4n π systems
topic Comment
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814197/
https://www.ncbi.nlm.nih.gov/pubmed/36697702
http://dx.doi.org/10.1038/s42004-021-00542-x
work_keys_str_mv AT otakei openquestionsinboronspecieswithglobally4npsystems
AT kinjorei openquestionsinboronspecieswithglobally4npsystems

Ejemplares similares