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Prediction of heptagonal bipyramidal nonacoordination in highly viable [OB-M©B(7)O(7)-BO](−) (M = Fe, Ru, Os) complexes

Non-spherical distributions of ligand atoms in coordination complexes are generally unfavorable due to higher repulsion than for spherical distributions. To the best of our knowledge, non-spherical heptagonal bipyramidal nonacoordination is hitherto unreported, because of extremely high repulsion am...

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Detalles Bibliográficos
Autores principales: Jin, Bo, Li, Hai-Ru, Wei, Zhihong, Yan, Miao, Yuan, Caixia, Wu, Yan-Bo, Li, Si-Dian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814638/
https://www.ncbi.nlm.nih.gov/pubmed/36697780
http://dx.doi.org/10.1038/s42004-021-00620-0

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