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Silylium ion mediated 2+2 cycloaddition leads to 4+2 Diels-Alder reaction products
The mechanism of silver(I) and copper(I) catalyzed cycloaddition between 1,2-diazines and siloxy alkynes remains controversial. Here we explore the mechanism of this reaction with density functional theory. Our calculations show that the reaction takes place through a metal (Ag(+), Cu(+)) catalyzed...
| Autores principales: | , |
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| 格式: | Online Artículo Texto |
| 語言: | English |
| 出版: |
Nature Publishing Group UK
2020
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| 主題: | |
| 在線閱讀: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814679/ https://www.ncbi.nlm.nih.gov/pubmed/36703398 http://dx.doi.org/10.1038/s42004-020-00373-2 |