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Open questions on aromaticity in organometallics

While sp(2)-hybridized carbon atoms in hydrocarbons typically contribute only one electron to their aromaticity, metals have more electrons from d or f orbitals available for participating in conjugation in organometallics, complicating the electron counting as well as analysis of their aromaticity....

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Detalles Bibliográficos
Autor principal: Zhu, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814701/
https://www.ncbi.nlm.nih.gov/pubmed/36703374
http://dx.doi.org/10.1038/s42004-020-00419-5