Physical properties of porphyrin-based crystalline metal‒organic frameworks

Metal‒organic frameworks (MOFs) are widely studied molecular assemblies that have demonstrated promise for a range of potential applications. Given the unique and well-established photophysical and electrochemical properties of porphyrins, porphyrin-based MOFs are emerging as promising candidates fo...

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Detalles Bibliográficos
Autores principales: Rajasree, Sreehari Surendran, Li, Xinlin, Deria, Pravas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Review Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814740/
https://www.ncbi.nlm.nih.gov/pubmed/36697594
http://dx.doi.org/10.1038/s42004-021-00484-4
Descripción
Sumario:Metal‒organic frameworks (MOFs) are widely studied molecular assemblies that have demonstrated promise for a range of potential applications. Given the unique and well-established photophysical and electrochemical properties of porphyrins, porphyrin-based MOFs are emerging as promising candidates for energy harvesting and conversion applications. Here we discuss the physical properties of porphyrin-based MOFs, highlighting the evolution of various optical and electronic features as a function of their modular framework structures and compositional variations.

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