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High-throughput screening for discovery of benchtop separations systems for selected rare earth elements

Rare earth (RE) elements (scandium, yttrium, and the lanthanides) are critical for their role in sustainable energy technologies. Problems with their supply chain have motivated research to improve separations methods to recycle these elements from end of life technology. Toward this goal, we report...

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Detalles Bibliográficos
Autores principales: Nelson, Joshua J. M., Cheisson, Thibault, Rugh, Haley J., Gau, Michael R., Carroll, Patrick J., Schelter, Eric J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814905/
https://www.ncbi.nlm.nih.gov/pubmed/36703327
http://dx.doi.org/10.1038/s42004-019-0253-x
Descripción
Sumario:Rare earth (RE) elements (scandium, yttrium, and the lanthanides) are critical for their role in sustainable energy technologies. Problems with their supply chain have motivated research to improve separations methods to recycle these elements from end of life technology. Toward this goal, we report the synthesis and characterization of the ligand tris[(1-hydroxy-2-oxo-1,2-dihydropyridine-3-carboxamido)ethyl]amine, H(3)1·TFA (TFA = trifluoroacetic acid), and complexes 1·RE (RE = La, Nd, Dy). A high-throughput experimentation (HTE) screen was developed to quantitatively determine the precipitation of 1·RE as a function of pH as well as equivalents of H(3)1·TFA. This method rapidly determines optimal conditions for the separation of RE mixtures, while minimizing materials consumption. The HTE-predicted conditions are used to achieve the lab-scale separation of Nd/Dy (SF(Nd/Dy) = 213 ± 34) and La/Nd (SF(La/Nd) = 16.2 ± 0.2) mixtures in acidic aqueous media.