trans-Bis(2,2′-di­pyridyl­amine-κ(2) N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II)

The title compound, [Cu(C(9)H(5)N(4)O)(2)(C(10)H(9)N(3))(2)], was synthesized solvothermally. The complex exhibits a distorted octa­hedral coordination geometry. The Cu(II) atom is located on an inversion centre. The distorted octahedral CuN(6) coordination sphere is composed of bidentate 2,2′-dipyr...

Descripción completa

Detalles Bibliográficos
Autores principales: Saadallah, Yaakoub, Setifi, Zouaoui, Geiger, David K., Al-Douh, Mohammed Hadi, Satour, Achouak, Setifi, Fatima
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815125/
https://www.ncbi.nlm.nih.gov/pubmed/36628191
http://dx.doi.org/10.1107/S2414314622011804
Descripción
Sumario:The title compound, [Cu(C(9)H(5)N(4)O)(2)(C(10)H(9)N(3))(2)], was synthesized solvothermally. The complex exhibits a distorted octa­hedral coordination geometry. The Cu(II) atom is located on an inversion centre. The distorted octahedral CuN(6) coordination sphere is composed of bidentate 2,2′-dipyrid­ylamine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetra­cyano-2-eth­oxy­propenide ligands. In the crystal, N—H⋯N hydrogen bonding results in chains parallel to [010]. [Image: see text]

Ejemplares similares