trans-Bis(2,2′-di­pyridyl­amine-κ(2) N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II)

The title compound, [Cu(C(9)H(5)N(4)O)(2)(C(10)H(9)N(3))(2)], was synthesized solvothermally. The complex exhibits a distorted octa­hedral coordination geometry. The Cu(II) atom is located on an inversion centre. The distorted octahedral CuN(6) coordination sphere is composed of bidentate 2,2′-dipyr...

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Autores principales: Saadallah, Yaakoub, Setifi, Zouaoui, Geiger, David K., Al-Douh, Mohammed Hadi, Satour, Achouak, Setifi, Fatima
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815125/
https://www.ncbi.nlm.nih.gov/pubmed/36628191
http://dx.doi.org/10.1107/S2414314622011804
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author Saadallah, Yaakoub
Setifi, Zouaoui
Geiger, David K.
Al-Douh, Mohammed Hadi
Satour, Achouak
Setifi, Fatima
author_facet Saadallah, Yaakoub
Setifi, Zouaoui
Geiger, David K.
Al-Douh, Mohammed Hadi
Satour, Achouak
Setifi, Fatima
author_sort Saadallah, Yaakoub
collection PubMed
description The title compound, [Cu(C(9)H(5)N(4)O)(2)(C(10)H(9)N(3))(2)], was synthesized solvothermally. The complex exhibits a distorted octa­hedral coordination geometry. The Cu(II) atom is located on an inversion centre. The distorted octahedral CuN(6) coordination sphere is composed of bidentate 2,2′-dipyrid­ylamine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetra­cyano-2-eth­oxy­propenide ligands. In the crystal, N—H⋯N hydrogen bonding results in chains parallel to [010]. [Image: see text]
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spelling pubmed-98151252023-01-09 trans-Bis(2,2′-di­pyridyl­amine-κ(2) N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II) Saadallah, Yaakoub Setifi, Zouaoui Geiger, David K. Al-Douh, Mohammed Hadi Satour, Achouak Setifi, Fatima IUCrdata Data Reports The title compound, [Cu(C(9)H(5)N(4)O)(2)(C(10)H(9)N(3))(2)], was synthesized solvothermally. The complex exhibits a distorted octa­hedral coordination geometry. The Cu(II) atom is located on an inversion centre. The distorted octahedral CuN(6) coordination sphere is composed of bidentate 2,2′-dipyrid­ylamine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetra­cyano-2-eth­oxy­propenide ligands. In the crystal, N—H⋯N hydrogen bonding results in chains parallel to [010]. [Image: see text] International Union of Crystallography 2022-12-23 /pmc/articles/PMC9815125/ /pubmed/36628191 http://dx.doi.org/10.1107/S2414314622011804 Text en © Saadallah et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Saadallah, Yaakoub
Setifi, Zouaoui
Geiger, David K.
Al-Douh, Mohammed Hadi
Satour, Achouak
Setifi, Fatima
trans-Bis(2,2′-di­pyridyl­amine-κ(2) N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II)
title trans-Bis(2,2′-di­pyridyl­amine-κ(2) N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II)
title_full trans-Bis(2,2′-di­pyridyl­amine-κ(2) N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II)
title_fullStr trans-Bis(2,2′-di­pyridyl­amine-κ(2) N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II)
title_full_unstemmed trans-Bis(2,2′-di­pyridyl­amine-κ(2) N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II)
title_short trans-Bis(2,2′-di­pyridyl­amine-κ(2) N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II)
title_sort trans-bis(2,2′-di­pyridyl­amine-κ(2) n,n′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κn)copper(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815125/
https://www.ncbi.nlm.nih.gov/pubmed/36628191
http://dx.doi.org/10.1107/S2414314622011804
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