Di­chlorido­(4,4′-dimethyl-2,2′-bi­pyridine-κ(2) N,N′)zinc(II) aceto­nitrile monosolvate

In the title complex, [ZnCl(2)(C(12)H(12)N(2))]·CH(3)CN, the zinc(II) atom is fourfold coordinated by two chloride ligands and a bidentate 4,4′-dimethyl-2,2′-bi­pyridine ligand in a distorted tetra­hedral shape with a mol­ecule of aceto­nitrile sitting in the outer coordination sphere of the complex...

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Detalles Bibliográficos
Autores principales: Adrian, Rafael A., Rios, Jadan J., Arman, Hadi D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815126/
https://www.ncbi.nlm.nih.gov/pubmed/36628194
http://dx.doi.org/10.1107/S241431462201149X
Descripción
Sumario:In the title complex, [ZnCl(2)(C(12)H(12)N(2))]·CH(3)CN, the zinc(II) atom is fourfold coordinated by two chloride ligands and a bidentate 4,4′-dimethyl-2,2′-bi­pyridine ligand in a distorted tetra­hedral shape with a mol­ecule of aceto­nitrile sitting in the outer coordination sphere of the complex. π–π stacking inter­actions between the pyridyl rings in adjacent mol­ecules contribute to the alignment of the complexes in columns parallel to the a axis. [Image: see text]

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