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(Nitrito-κ(2) O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I)
The molecular structure of the title compound, [Ag(NO(2))(C(21)H(21)P)(2)], exhibits a pseudo-tetrahedral coordination around the central Ag(I) atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P2(1)/n with a rather long b axis [33.8752 (2) Å]....
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815127/ https://www.ncbi.nlm.nih.gov/pubmed/36628189 http://dx.doi.org/10.1107/S2414314622011488 |
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author | Malan, Frederick P. Potgieter, Kariska Meijboom, Reinout |
author_facet | Malan, Frederick P. Potgieter, Kariska Meijboom, Reinout |
author_sort | Malan, Frederick P. |
collection | PubMed |
description | The molecular structure of the title compound, [Ag(NO(2))(C(21)H(21)P)(2)], exhibits a pseudo-tetrahedral coordination around the central Ag(I) atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P2(1)/n with a rather long b axis [33.8752 (2) Å]. Weak C—H⋯O and C—H⋯N interactions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry. [Image: see text] |
format | Online Article Text |
id | pubmed-9815127 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-98151272023-01-09 (Nitrito-κ(2) O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) Malan, Frederick P. Potgieter, Kariska Meijboom, Reinout IUCrdata Data Reports The molecular structure of the title compound, [Ag(NO(2))(C(21)H(21)P)(2)], exhibits a pseudo-tetrahedral coordination around the central Ag(I) atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P2(1)/n with a rather long b axis [33.8752 (2) Å]. Weak C—H⋯O and C—H⋯N interactions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry. [Image: see text] International Union of Crystallography 2022-12-06 /pmc/articles/PMC9815127/ /pubmed/36628189 http://dx.doi.org/10.1107/S2414314622011488 Text en © Malan et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Malan, Frederick P. Potgieter, Kariska Meijboom, Reinout (Nitrito-κ(2) O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
title | (Nitrito-κ(2)
O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
title_full | (Nitrito-κ(2)
O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
title_fullStr | (Nitrito-κ(2)
O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
title_full_unstemmed | (Nitrito-κ(2)
O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
title_short | (Nitrito-κ(2)
O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I) |
title_sort | (nitrito-κ(2)
o,o′)bis[tris(4-methylphenyl)phosphane-κp]silver(i) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815127/ https://www.ncbi.nlm.nih.gov/pubmed/36628189 http://dx.doi.org/10.1107/S2414314622011488 |
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