Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)

The mol­ecular structure of the title complex, [Ag(NO(3))(C(19)H(17)P)(3)], exhibits a severely distorted tetra­hedral coordination environment around the central Ag(I) atom, comprising one O and three P atoms. Apart from a primary Ag—O coordination of the nitrato ligand of 2.667 (3) Å, a second (we...

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Detalles Bibliográficos
Autores principales: Potgieter, Kariska, Malan, Frederick P., Alimi, Oyekunle Azeez, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815128/
https://www.ncbi.nlm.nih.gov/pubmed/36628192
http://dx.doi.org/10.1107/S2414314622011476
Descripción
Sumario:The mol­ecular structure of the title complex, [Ag(NO(3))(C(19)H(17)P)(3)], exhibits a severely distorted tetra­hedral coordination environment around the central Ag(I) atom, comprising one O and three P atoms. Apart from a primary Ag—O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary inter­action of the nitrato ligand via the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete mol­ecule in the asymmetric unit. Weak C—H⋯O inter­actions consolidate the packing. [Image: see text]

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