Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)

The mol­ecular structure of the title complex, [Ag(NO(3))(C(19)H(17)P)(3)], exhibits a severely distorted tetra­hedral coordination environment around the central Ag(I) atom, comprising one O and three P atoms. Apart from a primary Ag—O coordination of the nitrato ligand of 2.667 (3) Å, a second (we...

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Autores principales: Potgieter, Kariska, Malan, Frederick P., Alimi, Oyekunle Azeez, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815128/
https://www.ncbi.nlm.nih.gov/pubmed/36628192
http://dx.doi.org/10.1107/S2414314622011476
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author Potgieter, Kariska
Malan, Frederick P.
Alimi, Oyekunle Azeez
Meijboom, Reinout
author_facet Potgieter, Kariska
Malan, Frederick P.
Alimi, Oyekunle Azeez
Meijboom, Reinout
author_sort Potgieter, Kariska
collection PubMed
description The mol­ecular structure of the title complex, [Ag(NO(3))(C(19)H(17)P)(3)], exhibits a severely distorted tetra­hedral coordination environment around the central Ag(I) atom, comprising one O and three P atoms. Apart from a primary Ag—O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary inter­action of the nitrato ligand via the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete mol­ecule in the asymmetric unit. Weak C—H⋯O inter­actions consolidate the packing. [Image: see text]
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spelling pubmed-98151282023-01-09 Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I) Potgieter, Kariska Malan, Frederick P. Alimi, Oyekunle Azeez Meijboom, Reinout IUCrdata Data Reports The mol­ecular structure of the title complex, [Ag(NO(3))(C(19)H(17)P)(3)], exhibits a severely distorted tetra­hedral coordination environment around the central Ag(I) atom, comprising one O and three P atoms. Apart from a primary Ag—O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary inter­action of the nitrato ligand via the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete mol­ecule in the asymmetric unit. Weak C—H⋯O inter­actions consolidate the packing. [Image: see text] International Union of Crystallography 2022-12-06 /pmc/articles/PMC9815128/ /pubmed/36628192 http://dx.doi.org/10.1107/S2414314622011476 Text en © Potgieter et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Potgieter, Kariska
Malan, Frederick P.
Alimi, Oyekunle Azeez
Meijboom, Reinout
Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)
title Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)
title_full Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)
title_fullStr Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)
title_full_unstemmed Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)
title_short Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)
title_sort tris(benzyl­diphenyl­phosphane-κp)(nitrato-κo)silver(i)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815128/
https://www.ncbi.nlm.nih.gov/pubmed/36628192
http://dx.doi.org/10.1107/S2414314622011476
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AT meijboomreinout trisbenzyldiphenylphosphanekpnitratokosilveri

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