Crystal structures of polymerized lithium chloride and dimethyl sulfoxide in the form of {2LiCl·3DMSO}( n ) and {LiCl·DMSO}( n )

Two novel LiCl·DMSO polymer structures were created by combining dry LiCl salt with dimethyl sulfoxide (DMSO), namely, catena-poly[[chlorido­lithium(I)]-μ-(dimethyl sulfoxide)-κ(2) O:O-[chlorido­lithium(I)]-di-μ-(dimethyl sulfoxide)-κ(4) O:O], [Li(2)Cl(2)(C(2)H(6)OS)(3)]( n ), and catena-poly[lithiu...

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Autores principales: Valdez, Nichole R., Herman, David J., Nemer, Martin B., Rodriguez, Mark A., Allcorn, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815132/
https://www.ncbi.nlm.nih.gov/pubmed/36628363
http://dx.doi.org/10.1107/S2056989022011896
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author Valdez, Nichole R.
Herman, David J.
Nemer, Martin B.
Rodriguez, Mark A.
Allcorn, Eric
author_facet Valdez, Nichole R.
Herman, David J.
Nemer, Martin B.
Rodriguez, Mark A.
Allcorn, Eric
author_sort Valdez, Nichole R.
collection PubMed
description Two novel LiCl·DMSO polymer structures were created by combining dry LiCl salt with dimethyl sulfoxide (DMSO), namely, catena-poly[[chlorido­lithium(I)]-μ-(dimethyl sulfoxide)-κ(2) O:O-[chlorido­lithium(I)]-di-μ-(dimethyl sulfoxide)-κ(4) O:O], [Li(2)Cl(2)(C(2)H(6)OS)(3)]( n ), and catena-poly[lithium(I)-μ-chlorido-μ-(dimethyl sulfoxide)-κ(2) O:O], [LiCl(C(2)H(6)OS)]( n ). The initial synthesized phase had very small block-shaped crystals (<0.08 mm) with monoclinic symmetry and a 2 LiCl: 3 DMSO ratio. As the solution evaporated, a second phase formed with a plate-shaped crystal morphology. After about 20 minutes, large (>0.20 mm) octa­hedron-shaped crystals formed. The plate crystals and the octa­hedron crystals are the same tetra­gonal structure with a 1 LiCl: 1 DMSO ratio. These structures are reported and compared to other known LiCl·solvent compounds.
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spelling pubmed-98151322023-01-09 Crystal structures of polymerized lithium chloride and dimethyl sulfoxide in the form of {2LiCl·3DMSO}( n ) and {LiCl·DMSO}( n ) Valdez, Nichole R. Herman, David J. Nemer, Martin B. Rodriguez, Mark A. Allcorn, Eric Acta Crystallogr E Crystallogr Commun Research Communications Two novel LiCl·DMSO polymer structures were created by combining dry LiCl salt with dimethyl sulfoxide (DMSO), namely, catena-poly[[chlorido­lithium(I)]-μ-(dimethyl sulfoxide)-κ(2) O:O-[chlorido­lithium(I)]-di-μ-(dimethyl sulfoxide)-κ(4) O:O], [Li(2)Cl(2)(C(2)H(6)OS)(3)]( n ), and catena-poly[lithium(I)-μ-chlorido-μ-(dimethyl sulfoxide)-κ(2) O:O], [LiCl(C(2)H(6)OS)]( n ). The initial synthesized phase had very small block-shaped crystals (<0.08 mm) with monoclinic symmetry and a 2 LiCl: 3 DMSO ratio. As the solution evaporated, a second phase formed with a plate-shaped crystal morphology. After about 20 minutes, large (>0.20 mm) octa­hedron-shaped crystals formed. The plate crystals and the octa­hedron crystals are the same tetra­gonal structure with a 1 LiCl: 1 DMSO ratio. These structures are reported and compared to other known LiCl·solvent compounds. International Union of Crystallography 2023-01-01 /pmc/articles/PMC9815132/ /pubmed/36628363 http://dx.doi.org/10.1107/S2056989022011896 Text en © Valdez et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Valdez, Nichole R.
Herman, David J.
Nemer, Martin B.
Rodriguez, Mark A.
Allcorn, Eric
Crystal structures of polymerized lithium chloride and dimethyl sulfoxide in the form of {2LiCl·3DMSO}( n ) and {LiCl·DMSO}( n )
title Crystal structures of polymerized lithium chloride and dimethyl sulfoxide in the form of {2LiCl·3DMSO}( n ) and {LiCl·DMSO}( n )
title_full Crystal structures of polymerized lithium chloride and dimethyl sulfoxide in the form of {2LiCl·3DMSO}( n ) and {LiCl·DMSO}( n )
title_fullStr Crystal structures of polymerized lithium chloride and dimethyl sulfoxide in the form of {2LiCl·3DMSO}( n ) and {LiCl·DMSO}( n )
title_full_unstemmed Crystal structures of polymerized lithium chloride and dimethyl sulfoxide in the form of {2LiCl·3DMSO}( n ) and {LiCl·DMSO}( n )
title_short Crystal structures of polymerized lithium chloride and dimethyl sulfoxide in the form of {2LiCl·3DMSO}( n ) and {LiCl·DMSO}( n )
title_sort crystal structures of polymerized lithium chloride and dimethyl sulfoxide in the form of {2licl·3dmso}( n ) and {licl·dmso}( n )
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815132/
https://www.ncbi.nlm.nih.gov/pubmed/36628363
http://dx.doi.org/10.1107/S2056989022011896
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