Crystal structure of bis­(mesit­yl)(pyrrol-1-yl)borane

In the crystal structure of the title compound, C(22)H(26)BN, the B atom acts to reduce the delocalization of the nitro­gen lone-pair electron density into the pyrrole ring, so that the two N—C bonds increase in length to 1.4005 (14) and 1.3981 (14) Å. The N—B bond length is 1.4425 (15) Å, which is...

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Autores principales: Sahin, Onur, Wallis, John D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815137/
https://www.ncbi.nlm.nih.gov/pubmed/36628361
http://dx.doi.org/10.1107/S2056989022011768
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author Sahin, Onur
Wallis, John D.
author_facet Sahin, Onur
Wallis, John D.
author_sort Sahin, Onur
collection PubMed
description In the crystal structure of the title compound, C(22)H(26)BN, the B atom acts to reduce the delocalization of the nitro­gen lone-pair electron density into the pyrrole ring, so that the two N—C bonds increase in length to 1.4005 (14) and 1.3981 (14) Å. The N—B bond length is 1.4425 (15) Å, which is longer than a typical N—B bond because the nitro­gen lone pair is not fully available to participate in the bond.
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spelling pubmed-98151372023-01-09 Crystal structure of bis­(mesit­yl)(pyrrol-1-yl)borane Sahin, Onur Wallis, John D. Acta Crystallogr E Crystallogr Commun Research Communications In the crystal structure of the title compound, C(22)H(26)BN, the B atom acts to reduce the delocalization of the nitro­gen lone-pair electron density into the pyrrole ring, so that the two N—C bonds increase in length to 1.4005 (14) and 1.3981 (14) Å. The N—B bond length is 1.4425 (15) Å, which is longer than a typical N—B bond because the nitro­gen lone pair is not fully available to participate in the bond. International Union of Crystallography 2023-01-01 /pmc/articles/PMC9815137/ /pubmed/36628361 http://dx.doi.org/10.1107/S2056989022011768 Text en © Sahin and Wallis 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Sahin, Onur
Wallis, John D.
Crystal structure of bis­(mesit­yl)(pyrrol-1-yl)borane
title Crystal structure of bis­(mesit­yl)(pyrrol-1-yl)borane
title_full Crystal structure of bis­(mesit­yl)(pyrrol-1-yl)borane
title_fullStr Crystal structure of bis­(mesit­yl)(pyrrol-1-yl)borane
title_full_unstemmed Crystal structure of bis­(mesit­yl)(pyrrol-1-yl)borane
title_short Crystal structure of bis­(mesit­yl)(pyrrol-1-yl)borane
title_sort crystal structure of bis­(mesit­yl)(pyrrol-1-yl)borane
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815137/
https://www.ncbi.nlm.nih.gov/pubmed/36628361
http://dx.doi.org/10.1107/S2056989022011768
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