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Crystal structure of 2-(morpholino)ethyl­ammonium picrate monohydrate

The title compound, C(6)H(15)N(2)O(+)·C(6)H(2)N(3)O(7) (−)·H(2)O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C(6)H(15)N(2)O)(+), one anion (C(6)H(2)N(3)O(7))(−) and a water mol­ecule in the asymmet...

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Autores principales: Chidambaranathan, Balasubramanian, Sivaraj, Settu, Selvakumar, Shanmugam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815139/
https://www.ncbi.nlm.nih.gov/pubmed/36628364
http://dx.doi.org/10.1107/S2056989022011409
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author Chidambaranathan, Balasubramanian
Sivaraj, Settu
Selvakumar, Shanmugam
author_facet Chidambaranathan, Balasubramanian
Sivaraj, Settu
Selvakumar, Shanmugam
author_sort Chidambaranathan, Balasubramanian
collection PubMed
description The title compound, C(6)H(15)N(2)O(+)·C(6)H(2)N(3)O(7) (−)·H(2)O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C(6)H(15)N(2)O)(+), one anion (C(6)H(2)N(3)O(7))(−) and a water mol­ecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C—H⋯O, O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding inter­actions and π–π stacking. The inter­molecular inter­actions of the synthesized compound were qu­anti­fied by Hirshfeld surface analysis.
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spelling pubmed-98151392023-01-09 Crystal structure of 2-(morpholino)ethyl­ammonium picrate monohydrate Chidambaranathan, Balasubramanian Sivaraj, Settu Selvakumar, Shanmugam Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(6)H(15)N(2)O(+)·C(6)H(2)N(3)O(7) (−)·H(2)O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C(6)H(15)N(2)O)(+), one anion (C(6)H(2)N(3)O(7))(−) and a water mol­ecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C—H⋯O, O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding inter­actions and π–π stacking. The inter­molecular inter­actions of the synthesized compound were qu­anti­fied by Hirshfeld surface analysis. International Union of Crystallography 2023-01-01 /pmc/articles/PMC9815139/ /pubmed/36628364 http://dx.doi.org/10.1107/S2056989022011409 Text en © Chidambaranathan et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Chidambaranathan, Balasubramanian
Sivaraj, Settu
Selvakumar, Shanmugam
Crystal structure of 2-(morpholino)ethyl­ammonium picrate monohydrate
title Crystal structure of 2-(morpholino)ethyl­ammonium picrate monohydrate
title_full Crystal structure of 2-(morpholino)ethyl­ammonium picrate monohydrate
title_fullStr Crystal structure of 2-(morpholino)ethyl­ammonium picrate monohydrate
title_full_unstemmed Crystal structure of 2-(morpholino)ethyl­ammonium picrate monohydrate
title_short Crystal structure of 2-(morpholino)ethyl­ammonium picrate monohydrate
title_sort crystal structure of 2-(morpholino)ethyl­ammonium picrate monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815139/
https://www.ncbi.nlm.nih.gov/pubmed/36628364
http://dx.doi.org/10.1107/S2056989022011409
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