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Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate
The title compound, C(6)H(15)N(2)O(+)·C(6)H(2)N(3)O(7) (−)·H(2)O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C(6)H(15)N(2)O)(+), one anion (C(6)H(2)N(3)O(7))(−) and a water molecule in the asymmet...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815139/ https://www.ncbi.nlm.nih.gov/pubmed/36628364 http://dx.doi.org/10.1107/S2056989022011409 |
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author | Chidambaranathan, Balasubramanian Sivaraj, Settu Selvakumar, Shanmugam |
author_facet | Chidambaranathan, Balasubramanian Sivaraj, Settu Selvakumar, Shanmugam |
author_sort | Chidambaranathan, Balasubramanian |
collection | PubMed |
description | The title compound, C(6)H(15)N(2)O(+)·C(6)H(2)N(3)O(7) (−)·H(2)O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C(6)H(15)N(2)O)(+), one anion (C(6)H(2)N(3)O(7))(−) and a water molecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C—H⋯O, O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding interactions and π–π stacking. The intermolecular interactions of the synthesized compound were quantified by Hirshfeld surface analysis. |
format | Online Article Text |
id | pubmed-9815139 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-98151392023-01-09 Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate Chidambaranathan, Balasubramanian Sivaraj, Settu Selvakumar, Shanmugam Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(6)H(15)N(2)O(+)·C(6)H(2)N(3)O(7) (−)·H(2)O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C(6)H(15)N(2)O)(+), one anion (C(6)H(2)N(3)O(7))(−) and a water molecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C—H⋯O, O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding interactions and π–π stacking. The intermolecular interactions of the synthesized compound were quantified by Hirshfeld surface analysis. International Union of Crystallography 2023-01-01 /pmc/articles/PMC9815139/ /pubmed/36628364 http://dx.doi.org/10.1107/S2056989022011409 Text en © Chidambaranathan et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Chidambaranathan, Balasubramanian Sivaraj, Settu Selvakumar, Shanmugam Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate |
title | Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate |
title_full | Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate |
title_fullStr | Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate |
title_full_unstemmed | Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate |
title_short | Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate |
title_sort | crystal structure of 2-(morpholino)ethylammonium picrate monohydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9815139/ https://www.ncbi.nlm.nih.gov/pubmed/36628364 http://dx.doi.org/10.1107/S2056989022011409 |
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