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Non-Noble-Metal Mono and Bimetallic Composites for Efficient Electrocatalysis of Phosphine Oxide and Acetylene C-H/P-H Coupling under Mild Conditions

The present work describes an efficient reaction of electrochemical phosphorylation of phenylacetylene controlled by the composition of catalytic nanoparticles based on non-noble-metals. The sought-after products are produced via the simple synthetic protocol based on room temperature, atom-economic...

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Detalles Bibliográficos
Autores principales: Tarasov, Maxim V., Bochkova, Olga D., Gryaznova, Tatyana V., Mustafina, Asiya R., Budnikova, Yulia H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9821134/
https://www.ncbi.nlm.nih.gov/pubmed/36614210
http://dx.doi.org/10.3390/ijms24010765
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author Tarasov, Maxim V.
Bochkova, Olga D.
Gryaznova, Tatyana V.
Mustafina, Asiya R.
Budnikova, Yulia H.
author_facet Tarasov, Maxim V.
Bochkova, Olga D.
Gryaznova, Tatyana V.
Mustafina, Asiya R.
Budnikova, Yulia H.
author_sort Tarasov, Maxim V.
collection PubMed
description The present work describes an efficient reaction of electrochemical phosphorylation of phenylacetylene controlled by the composition of catalytic nanoparticles based on non-noble-metals. The sought-after products are produced via the simple synthetic protocol based on room temperature, atom-economical reactions, and silica nanoparticles (SNs) loaded by one or two d-metal ions as nanocatalysts. The redox and catalytic properties of SNs can be tuned with a range of parameters, such as compositions of the bimetallic systems, their preparation method, and morphology. Monometallic SNs give phosphorylated acetylene with retention of the triple bond, and bimetallic SNs give a bis-phosphorylation product. This is the first example of acetylene and phosphine oxide C-H/P-H coupling with a regenerable and recyclable catalyst.
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spelling pubmed-98211342023-01-07 Non-Noble-Metal Mono and Bimetallic Composites for Efficient Electrocatalysis of Phosphine Oxide and Acetylene C-H/P-H Coupling under Mild Conditions Tarasov, Maxim V. Bochkova, Olga D. Gryaznova, Tatyana V. Mustafina, Asiya R. Budnikova, Yulia H. Int J Mol Sci Article The present work describes an efficient reaction of electrochemical phosphorylation of phenylacetylene controlled by the composition of catalytic nanoparticles based on non-noble-metals. The sought-after products are produced via the simple synthetic protocol based on room temperature, atom-economical reactions, and silica nanoparticles (SNs) loaded by one or two d-metal ions as nanocatalysts. The redox and catalytic properties of SNs can be tuned with a range of parameters, such as compositions of the bimetallic systems, their preparation method, and morphology. Monometallic SNs give phosphorylated acetylene with retention of the triple bond, and bimetallic SNs give a bis-phosphorylation product. This is the first example of acetylene and phosphine oxide C-H/P-H coupling with a regenerable and recyclable catalyst. MDPI 2023-01-01 /pmc/articles/PMC9821134/ /pubmed/36614210 http://dx.doi.org/10.3390/ijms24010765 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Tarasov, Maxim V.
Bochkova, Olga D.
Gryaznova, Tatyana V.
Mustafina, Asiya R.
Budnikova, Yulia H.
Non-Noble-Metal Mono and Bimetallic Composites for Efficient Electrocatalysis of Phosphine Oxide and Acetylene C-H/P-H Coupling under Mild Conditions
title Non-Noble-Metal Mono and Bimetallic Composites for Efficient Electrocatalysis of Phosphine Oxide and Acetylene C-H/P-H Coupling under Mild Conditions
title_full Non-Noble-Metal Mono and Bimetallic Composites for Efficient Electrocatalysis of Phosphine Oxide and Acetylene C-H/P-H Coupling under Mild Conditions
title_fullStr Non-Noble-Metal Mono and Bimetallic Composites for Efficient Electrocatalysis of Phosphine Oxide and Acetylene C-H/P-H Coupling under Mild Conditions
title_full_unstemmed Non-Noble-Metal Mono and Bimetallic Composites for Efficient Electrocatalysis of Phosphine Oxide and Acetylene C-H/P-H Coupling under Mild Conditions
title_short Non-Noble-Metal Mono and Bimetallic Composites for Efficient Electrocatalysis of Phosphine Oxide and Acetylene C-H/P-H Coupling under Mild Conditions
title_sort non-noble-metal mono and bimetallic composites for efficient electrocatalysis of phosphine oxide and acetylene c-h/p-h coupling under mild conditions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9821134/
https://www.ncbi.nlm.nih.gov/pubmed/36614210
http://dx.doi.org/10.3390/ijms24010765
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