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Organic Anode Materials for Lithium-Ion Batteries: Recent Progress and Challenges

In the search for novel anode materials for lithium-ion batteries (LIBs), organic electrode materials have recently attracted substantial attention and seem to be the next preferred candidates for use as high-performance anode materials in rechargeable LIBs due to their low cost, high theoretical ca...

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Autores principales: Pavlovskii, Alexander A., Pushnitsa, Konstantin, Kosenko, Alexandra, Novikov, Pavel, Popovich, Anatoliy A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9822040/
https://www.ncbi.nlm.nih.gov/pubmed/36614515
http://dx.doi.org/10.3390/ma16010177
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author Pavlovskii, Alexander A.
Pushnitsa, Konstantin
Kosenko, Alexandra
Novikov, Pavel
Popovich, Anatoliy A.
author_facet Pavlovskii, Alexander A.
Pushnitsa, Konstantin
Kosenko, Alexandra
Novikov, Pavel
Popovich, Anatoliy A.
author_sort Pavlovskii, Alexander A.
collection PubMed
description In the search for novel anode materials for lithium-ion batteries (LIBs), organic electrode materials have recently attracted substantial attention and seem to be the next preferred candidates for use as high-performance anode materials in rechargeable LIBs due to their low cost, high theoretical capacity, structural diversity, environmental friendliness, and facile synthesis. Up to now, the electrochemical properties of numerous organic compounds with different functional groups (carbonyl, azo, sulfur, imine, etc.) have been thoroughly explored as anode materials for LIBs, dividing organic anode materials into four main classes: organic carbonyl compounds, covalent organic frameworks (COFs), metal-organic frameworks (MOFs), and organic compounds with nitrogen-containing groups. In this review, an overview of the recent progress in organic anodes is provided. The electrochemical performances of different organic anode materials are compared, revealing the advantages and disadvantages of each class of organic materials in both research and commercial applications. Afterward, the practical applications of some organic anode materials in full cells of LIBs are provided. Finally, some techniques to address significant issues, such as poor electronic conductivity, low discharge voltage, and undesired dissolution of active organic anode material into typical organic electrolytes, are discussed. This paper will guide the study of more efficient organic compounds that can be employed as high-performance anode materials in LIBs.
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spelling pubmed-98220402023-01-07 Organic Anode Materials for Lithium-Ion Batteries: Recent Progress and Challenges Pavlovskii, Alexander A. Pushnitsa, Konstantin Kosenko, Alexandra Novikov, Pavel Popovich, Anatoliy A. Materials (Basel) Review In the search for novel anode materials for lithium-ion batteries (LIBs), organic electrode materials have recently attracted substantial attention and seem to be the next preferred candidates for use as high-performance anode materials in rechargeable LIBs due to their low cost, high theoretical capacity, structural diversity, environmental friendliness, and facile synthesis. Up to now, the electrochemical properties of numerous organic compounds with different functional groups (carbonyl, azo, sulfur, imine, etc.) have been thoroughly explored as anode materials for LIBs, dividing organic anode materials into four main classes: organic carbonyl compounds, covalent organic frameworks (COFs), metal-organic frameworks (MOFs), and organic compounds with nitrogen-containing groups. In this review, an overview of the recent progress in organic anodes is provided. The electrochemical performances of different organic anode materials are compared, revealing the advantages and disadvantages of each class of organic materials in both research and commercial applications. Afterward, the practical applications of some organic anode materials in full cells of LIBs are provided. Finally, some techniques to address significant issues, such as poor electronic conductivity, low discharge voltage, and undesired dissolution of active organic anode material into typical organic electrolytes, are discussed. This paper will guide the study of more efficient organic compounds that can be employed as high-performance anode materials in LIBs. MDPI 2022-12-25 /pmc/articles/PMC9822040/ /pubmed/36614515 http://dx.doi.org/10.3390/ma16010177 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Pavlovskii, Alexander A.
Pushnitsa, Konstantin
Kosenko, Alexandra
Novikov, Pavel
Popovich, Anatoliy A.
Organic Anode Materials for Lithium-Ion Batteries: Recent Progress and Challenges
title Organic Anode Materials for Lithium-Ion Batteries: Recent Progress and Challenges
title_full Organic Anode Materials for Lithium-Ion Batteries: Recent Progress and Challenges
title_fullStr Organic Anode Materials for Lithium-Ion Batteries: Recent Progress and Challenges
title_full_unstemmed Organic Anode Materials for Lithium-Ion Batteries: Recent Progress and Challenges
title_short Organic Anode Materials for Lithium-Ion Batteries: Recent Progress and Challenges
title_sort organic anode materials for lithium-ion batteries: recent progress and challenges
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9822040/
https://www.ncbi.nlm.nih.gov/pubmed/36614515
http://dx.doi.org/10.3390/ma16010177
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