Adsorption of Wormlike Chains onto Partially Permeable Membranes

Reversible adsorption of a single stiff wormlike macromolecule to flat membranes with various permeabilities is considered theoretically. It is shown that the adsorbed layer microstructure is significantly different from either a flexible chain or a stiff chain adsorption at a solid surface. Close to the critical point, the adsorbing wormlike chain forms a strongly anisotropic proximal layer near the membrane in addition to a nearly isotropic distal layer. The proximal layer is characterized by the algebraic monomer concentration profile, [Formula: see text] , due to the self-similar distribution of aligned polymer loops. For a perfectly penetrable membrane, [Formula: see text] which is different from [Formula: see text] obtained for semiflexible chain adsorption at a solid surface. Moreover, we establish that the critical exponent for a partially permeable membrane depends on its properties (porosity w) and propose an asymptotically exact theory (based on the generalized Edwards equation) predicting this dependence, [Formula: see text]. We also develop a scaling theory elucidating, in particular, an intricate competition of loops and tails in both proximal and distal sublayers.