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Biocompatible Piezoelectric PVDF/HA/AgNO(3) Thin Film Prepared by the Solvent Casting Method

In this study, new composites based on polyvinylidene fluoride (PVDF) were ornamented and prepared with hydroxyapatite (HA) and silver nitride (AgNO(3)). Taking into account the polarity of the solvent dimethyl sulfoxide, this solvent was used to disperse the particles. The aim of using DMSO was to...

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Autores principales: Markuniene, Ieva, Rabiei, Marzieh, Nasiri, Sohrab, Urbaite, Sigita, Palevicius, Arvydas, Janusas, Giedrius
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9823978/
https://www.ncbi.nlm.nih.gov/pubmed/36616887
http://dx.doi.org/10.3390/s23010289
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author Markuniene, Ieva
Rabiei, Marzieh
Nasiri, Sohrab
Urbaite, Sigita
Palevicius, Arvydas
Janusas, Giedrius
author_facet Markuniene, Ieva
Rabiei, Marzieh
Nasiri, Sohrab
Urbaite, Sigita
Palevicius, Arvydas
Janusas, Giedrius
author_sort Markuniene, Ieva
collection PubMed
description In this study, new composites based on polyvinylidene fluoride (PVDF) were ornamented and prepared with hydroxyapatite (HA) and silver nitride (AgNO(3)). Taking into account the polarity of the solvent dimethyl sulfoxide, this solvent was used to disperse the particles. The aim of using DMSO was to create amorphous phases and the strong dipoles of the C–F bond to reduce the energy barrier and improve the electrical properties. The PVDF played the role of matrix in HA, and AgNO(3) was used as reinforcing elements. X-ray diffraction of the samples directly showed the amorphous phase and mixed amorphous and crystalline phases when all three materials were used simultaneously for preparing the composite. The scanning electron microscopy (SEM) images of the samples confirmed the role of PVDF, HA, and AgNO(3). Furthermore, the energy dispersive X-ray (EDX) analysis was performed and proved that the HA structure did not change when the ratio of [Formula: see text] was equal to the ratio of natural HA. The electrical properties were investigated, and the amount of energy ranged from 56.50 to 125.20 mV. The final results showed that a designed device consisting of an active layer made of 0.1 g HA:0.5 g PVDF showed the highest energy barrier, the highest polarity, and surface energy, thus proving its relevance as potential material for energy harvesting applications.
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spelling pubmed-98239782023-01-08 Biocompatible Piezoelectric PVDF/HA/AgNO(3) Thin Film Prepared by the Solvent Casting Method Markuniene, Ieva Rabiei, Marzieh Nasiri, Sohrab Urbaite, Sigita Palevicius, Arvydas Janusas, Giedrius Sensors (Basel) Article In this study, new composites based on polyvinylidene fluoride (PVDF) were ornamented and prepared with hydroxyapatite (HA) and silver nitride (AgNO(3)). Taking into account the polarity of the solvent dimethyl sulfoxide, this solvent was used to disperse the particles. The aim of using DMSO was to create amorphous phases and the strong dipoles of the C–F bond to reduce the energy barrier and improve the electrical properties. The PVDF played the role of matrix in HA, and AgNO(3) was used as reinforcing elements. X-ray diffraction of the samples directly showed the amorphous phase and mixed amorphous and crystalline phases when all three materials were used simultaneously for preparing the composite. The scanning electron microscopy (SEM) images of the samples confirmed the role of PVDF, HA, and AgNO(3). Furthermore, the energy dispersive X-ray (EDX) analysis was performed and proved that the HA structure did not change when the ratio of [Formula: see text] was equal to the ratio of natural HA. The electrical properties were investigated, and the amount of energy ranged from 56.50 to 125.20 mV. The final results showed that a designed device consisting of an active layer made of 0.1 g HA:0.5 g PVDF showed the highest energy barrier, the highest polarity, and surface energy, thus proving its relevance as potential material for energy harvesting applications. MDPI 2022-12-27 /pmc/articles/PMC9823978/ /pubmed/36616887 http://dx.doi.org/10.3390/s23010289 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Markuniene, Ieva
Rabiei, Marzieh
Nasiri, Sohrab
Urbaite, Sigita
Palevicius, Arvydas
Janusas, Giedrius
Biocompatible Piezoelectric PVDF/HA/AgNO(3) Thin Film Prepared by the Solvent Casting Method
title Biocompatible Piezoelectric PVDF/HA/AgNO(3) Thin Film Prepared by the Solvent Casting Method
title_full Biocompatible Piezoelectric PVDF/HA/AgNO(3) Thin Film Prepared by the Solvent Casting Method
title_fullStr Biocompatible Piezoelectric PVDF/HA/AgNO(3) Thin Film Prepared by the Solvent Casting Method
title_full_unstemmed Biocompatible Piezoelectric PVDF/HA/AgNO(3) Thin Film Prepared by the Solvent Casting Method
title_short Biocompatible Piezoelectric PVDF/HA/AgNO(3) Thin Film Prepared by the Solvent Casting Method
title_sort biocompatible piezoelectric pvdf/ha/agno(3) thin film prepared by the solvent casting method
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9823978/
https://www.ncbi.nlm.nih.gov/pubmed/36616887
http://dx.doi.org/10.3390/s23010289
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