Cargando…
Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals
Biomass energy has attracted widespread attention due to its renewable, storage, huge production and clean and pollution-free advantages. Using Robinia pseudoacacia bark (RPB) as raw material, biogas and bio-oil produced by pyrolysis of RPB were detected and analyzed by TG-DTG, TG-FTIR and PY-GC-MS...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9824563/ https://www.ncbi.nlm.nih.gov/pubmed/36616464 http://dx.doi.org/10.3390/polym15010114 |
_version_ | 1784866440924364800 |
---|---|
author | Yue, Xiaochen Chen, Xiangmeng Li, Hanyin Ge, Shengbo Yang, Yafeng Peng, Wanxi |
author_facet | Yue, Xiaochen Chen, Xiangmeng Li, Hanyin Ge, Shengbo Yang, Yafeng Peng, Wanxi |
author_sort | Yue, Xiaochen |
collection | PubMed |
description | Biomass energy has attracted widespread attention due to its renewable, storage, huge production and clean and pollution-free advantages. Using Robinia pseudoacacia bark (RPB) as raw material, biogas and bio-oil produced by pyrolysis of RPB were detected and analyzed by TG-DTG, TG-FTIR and PY-GC-MS under the action of nanocatalysis. TG results showed that CH(4) and CO flammable gases were produced by pyrolysis. PY-GC-MS results showed that RPB was rapidly pyrolyzed to obtain alcohols, ketones, aldehydes and acids bio-oil. The content of phenolic substances was the highest, accounting for 32.18% of all substances.Nanocatalysis has a certain effect on RPB, accelerating the precipitation of pyrolysis products and improving the over-oxidation of bio-oil. In addition, the extracts of RPB were identified and analyzed by FTIR, NMR, GC-MS and LC-Q-TOF-MS, and more than 100 active ingredients, such as Betaine, Epicathin and β-sitosterol, were detected. Their applications as additive energy in other fields were explored. Therefore, Robinia pseudoacacia bark constitutes a fine biofeedstock for biofuels and biochemicals. |
format | Online Article Text |
id | pubmed-9824563 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-98245632023-01-08 Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals Yue, Xiaochen Chen, Xiangmeng Li, Hanyin Ge, Shengbo Yang, Yafeng Peng, Wanxi Polymers (Basel) Article Biomass energy has attracted widespread attention due to its renewable, storage, huge production and clean and pollution-free advantages. Using Robinia pseudoacacia bark (RPB) as raw material, biogas and bio-oil produced by pyrolysis of RPB were detected and analyzed by TG-DTG, TG-FTIR and PY-GC-MS under the action of nanocatalysis. TG results showed that CH(4) and CO flammable gases were produced by pyrolysis. PY-GC-MS results showed that RPB was rapidly pyrolyzed to obtain alcohols, ketones, aldehydes and acids bio-oil. The content of phenolic substances was the highest, accounting for 32.18% of all substances.Nanocatalysis has a certain effect on RPB, accelerating the precipitation of pyrolysis products and improving the over-oxidation of bio-oil. In addition, the extracts of RPB were identified and analyzed by FTIR, NMR, GC-MS and LC-Q-TOF-MS, and more than 100 active ingredients, such as Betaine, Epicathin and β-sitosterol, were detected. Their applications as additive energy in other fields were explored. Therefore, Robinia pseudoacacia bark constitutes a fine biofeedstock for biofuels and biochemicals. MDPI 2022-12-27 /pmc/articles/PMC9824563/ /pubmed/36616464 http://dx.doi.org/10.3390/polym15010114 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Yue, Xiaochen Chen, Xiangmeng Li, Hanyin Ge, Shengbo Yang, Yafeng Peng, Wanxi Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals |
title | Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals |
title_full | Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals |
title_fullStr | Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals |
title_full_unstemmed | Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals |
title_short | Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals |
title_sort | nano ag/co(3)o(4) catalyzed rapid decomposition of robinia pseudoacacia bark for production biofuels and biochemicals |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9824563/ https://www.ncbi.nlm.nih.gov/pubmed/36616464 http://dx.doi.org/10.3390/polym15010114 |
work_keys_str_mv | AT yuexiaochen nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals AT chenxiangmeng nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals AT lihanyin nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals AT geshengbo nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals AT yangyafeng nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals AT pengwanxi nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals |