Cargando…

Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals

Biomass energy has attracted widespread attention due to its renewable, storage, huge production and clean and pollution-free advantages. Using Robinia pseudoacacia bark (RPB) as raw material, biogas and bio-oil produced by pyrolysis of RPB were detected and analyzed by TG-DTG, TG-FTIR and PY-GC-MS...

Descripción completa

Detalles Bibliográficos
Autores principales: Yue, Xiaochen, Chen, Xiangmeng, Li, Hanyin, Ge, Shengbo, Yang, Yafeng, Peng, Wanxi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9824563/
https://www.ncbi.nlm.nih.gov/pubmed/36616464
http://dx.doi.org/10.3390/polym15010114
_version_ 1784866440924364800
author Yue, Xiaochen
Chen, Xiangmeng
Li, Hanyin
Ge, Shengbo
Yang, Yafeng
Peng, Wanxi
author_facet Yue, Xiaochen
Chen, Xiangmeng
Li, Hanyin
Ge, Shengbo
Yang, Yafeng
Peng, Wanxi
author_sort Yue, Xiaochen
collection PubMed
description Biomass energy has attracted widespread attention due to its renewable, storage, huge production and clean and pollution-free advantages. Using Robinia pseudoacacia bark (RPB) as raw material, biogas and bio-oil produced by pyrolysis of RPB were detected and analyzed by TG-DTG, TG-FTIR and PY-GC-MS under the action of nanocatalysis. TG results showed that CH(4) and CO flammable gases were produced by pyrolysis. PY-GC-MS results showed that RPB was rapidly pyrolyzed to obtain alcohols, ketones, aldehydes and acids bio-oil. The content of phenolic substances was the highest, accounting for 32.18% of all substances.Nanocatalysis has a certain effect on RPB, accelerating the precipitation of pyrolysis products and improving the over-oxidation of bio-oil. In addition, the extracts of RPB were identified and analyzed by FTIR, NMR, GC-MS and LC-Q-TOF-MS, and more than 100 active ingredients, such as Betaine, Epicathin and β-sitosterol, were detected. Their applications as additive energy in other fields were explored. Therefore, Robinia pseudoacacia bark constitutes a fine biofeedstock for biofuels and biochemicals.
format Online
Article
Text
id pubmed-9824563
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-98245632023-01-08 Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals Yue, Xiaochen Chen, Xiangmeng Li, Hanyin Ge, Shengbo Yang, Yafeng Peng, Wanxi Polymers (Basel) Article Biomass energy has attracted widespread attention due to its renewable, storage, huge production and clean and pollution-free advantages. Using Robinia pseudoacacia bark (RPB) as raw material, biogas and bio-oil produced by pyrolysis of RPB were detected and analyzed by TG-DTG, TG-FTIR and PY-GC-MS under the action of nanocatalysis. TG results showed that CH(4) and CO flammable gases were produced by pyrolysis. PY-GC-MS results showed that RPB was rapidly pyrolyzed to obtain alcohols, ketones, aldehydes and acids bio-oil. The content of phenolic substances was the highest, accounting for 32.18% of all substances.Nanocatalysis has a certain effect on RPB, accelerating the precipitation of pyrolysis products and improving the over-oxidation of bio-oil. In addition, the extracts of RPB were identified and analyzed by FTIR, NMR, GC-MS and LC-Q-TOF-MS, and more than 100 active ingredients, such as Betaine, Epicathin and β-sitosterol, were detected. Their applications as additive energy in other fields were explored. Therefore, Robinia pseudoacacia bark constitutes a fine biofeedstock for biofuels and biochemicals. MDPI 2022-12-27 /pmc/articles/PMC9824563/ /pubmed/36616464 http://dx.doi.org/10.3390/polym15010114 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yue, Xiaochen
Chen, Xiangmeng
Li, Hanyin
Ge, Shengbo
Yang, Yafeng
Peng, Wanxi
Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals
title Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals
title_full Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals
title_fullStr Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals
title_full_unstemmed Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals
title_short Nano Ag/Co(3)O(4) Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals
title_sort nano ag/co(3)o(4) catalyzed rapid decomposition of robinia pseudoacacia bark for production biofuels and biochemicals
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9824563/
https://www.ncbi.nlm.nih.gov/pubmed/36616464
http://dx.doi.org/10.3390/polym15010114
work_keys_str_mv AT yuexiaochen nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals
AT chenxiangmeng nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals
AT lihanyin nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals
AT geshengbo nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals
AT yangyafeng nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals
AT pengwanxi nanoagco3o4catalyzedrapiddecompositionofrobiniapseudoacaciabarkforproductionbiofuelsandbiochemicals