The Unprecedented [S(4)N(2)O(10)](2−) Anion in the Molecular Gold Complexes [Au(2)Br(2)(S(4)N(2)O(10))(2)] and [Au(2)Cl(2)(S(4)N(2)O(10))(2)](S(2)O(5)Cl(2))

The reaction of hexachlorophosphazene, P(3)N(3)Cl(6), with SO(3) and the gold halides AuCl(3) and AuBr(3), respectively, leads to the new cyclic anionic tetramer, [S(4)N(2)O(10)](2−), which is coordinated to Au(3+) in the dimeric complexes [Au(2) X (2)(S(4)N(2)O(10))(2)] (X=Cl, Br). The [S(4)N(2)O(1...

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Detalles Bibliográficos
Autores principales: Rennebaum, Tobias, van Gerven, David, Wickleder, Mathias S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9825932/
https://www.ncbi.nlm.nih.gov/pubmed/35975981
http://dx.doi.org/10.1002/chem.202202171
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author Rennebaum, Tobias
van Gerven, David
Wickleder, Mathias S.
author_facet Rennebaum, Tobias
van Gerven, David
Wickleder, Mathias S.
author_sort Rennebaum, Tobias
collection PubMed
description The reaction of hexachlorophosphazene, P(3)N(3)Cl(6), with SO(3) and the gold halides AuCl(3) and AuBr(3), respectively, leads to the new cyclic anionic tetramer, [S(4)N(2)O(10)](2−), which is coordinated to Au(3+) in the dimeric complexes [Au(2) X (2)(S(4)N(2)O(10))(2)] (X=Cl, Br). The [S(4)N(2)O(10)](2−) anion can be seen as the condensation product of two sulfate anions, [SO(4)](2−) (,) and two amidosulfate anions, [NH(2)SO(3)](−).
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spelling pubmed-98259322023-01-09 The Unprecedented [S(4)N(2)O(10)](2−) Anion in the Molecular Gold Complexes [Au(2)Br(2)(S(4)N(2)O(10))(2)] and [Au(2)Cl(2)(S(4)N(2)O(10))(2)](S(2)O(5)Cl(2)) Rennebaum, Tobias van Gerven, David Wickleder, Mathias S. Chemistry Research Articles The reaction of hexachlorophosphazene, P(3)N(3)Cl(6), with SO(3) and the gold halides AuCl(3) and AuBr(3), respectively, leads to the new cyclic anionic tetramer, [S(4)N(2)O(10)](2−), which is coordinated to Au(3+) in the dimeric complexes [Au(2) X (2)(S(4)N(2)O(10))(2)] (X=Cl, Br). The [S(4)N(2)O(10)](2−) anion can be seen as the condensation product of two sulfate anions, [SO(4)](2−) (,) and two amidosulfate anions, [NH(2)SO(3)](−). John Wiley and Sons Inc. 2022-09-19 2022-11-21 /pmc/articles/PMC9825932/ /pubmed/35975981 http://dx.doi.org/10.1002/chem.202202171 Text en © 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ (https://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Research Articles
Rennebaum, Tobias
van Gerven, David
Wickleder, Mathias S.
The Unprecedented [S(4)N(2)O(10)](2−) Anion in the Molecular Gold Complexes [Au(2)Br(2)(S(4)N(2)O(10))(2)] and [Au(2)Cl(2)(S(4)N(2)O(10))(2)](S(2)O(5)Cl(2))
title The Unprecedented [S(4)N(2)O(10)](2−) Anion in the Molecular Gold Complexes [Au(2)Br(2)(S(4)N(2)O(10))(2)] and [Au(2)Cl(2)(S(4)N(2)O(10))(2)](S(2)O(5)Cl(2))
title_full The Unprecedented [S(4)N(2)O(10)](2−) Anion in the Molecular Gold Complexes [Au(2)Br(2)(S(4)N(2)O(10))(2)] and [Au(2)Cl(2)(S(4)N(2)O(10))(2)](S(2)O(5)Cl(2))
title_fullStr The Unprecedented [S(4)N(2)O(10)](2−) Anion in the Molecular Gold Complexes [Au(2)Br(2)(S(4)N(2)O(10))(2)] and [Au(2)Cl(2)(S(4)N(2)O(10))(2)](S(2)O(5)Cl(2))
title_full_unstemmed The Unprecedented [S(4)N(2)O(10)](2−) Anion in the Molecular Gold Complexes [Au(2)Br(2)(S(4)N(2)O(10))(2)] and [Au(2)Cl(2)(S(4)N(2)O(10))(2)](S(2)O(5)Cl(2))
title_short The Unprecedented [S(4)N(2)O(10)](2−) Anion in the Molecular Gold Complexes [Au(2)Br(2)(S(4)N(2)O(10))(2)] and [Au(2)Cl(2)(S(4)N(2)O(10))(2)](S(2)O(5)Cl(2))
title_sort unprecedented [s(4)n(2)o(10)](2−) anion in the molecular gold complexes [au(2)br(2)(s(4)n(2)o(10))(2)] and [au(2)cl(2)(s(4)n(2)o(10))(2)](s(2)o(5)cl(2))
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9825932/
https://www.ncbi.nlm.nih.gov/pubmed/35975981
http://dx.doi.org/10.1002/chem.202202171
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