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The Unprecedented [S(4)N(2)O(10)](2−) Anion in the Molecular Gold Complexes [Au(2)Br(2)(S(4)N(2)O(10))(2)] and [Au(2)Cl(2)(S(4)N(2)O(10))(2)](S(2)O(5)Cl(2))
The reaction of hexachlorophosphazene, P(3)N(3)Cl(6), with SO(3) and the gold halides AuCl(3) and AuBr(3), respectively, leads to the new cyclic anionic tetramer, [S(4)N(2)O(10)](2−), which is coordinated to Au(3+) in the dimeric complexes [Au(2) X (2)(S(4)N(2)O(10))(2)] (X=Cl, Br). The [S(4)N(2)O(1...
Autores principales: | Rennebaum, Tobias, van Gerven, David, Wickleder, Mathias S. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9825932/ https://www.ncbi.nlm.nih.gov/pubmed/35975981 http://dx.doi.org/10.1002/chem.202202171 |
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