Chemo‐ and Regioselective Multiple C(sp(2))−H Insertions of Malonate Metal Carbenes for Late‐Stage Functionalizations of Azahelicenes

Chiral quinacridines react up to four times, step‐by‐step, with α‐diazomalonates under Ru(II) and Rh(II) catalysis. By selecting the catalyst, [CpRu(CH(3)CN)(3)][PF(6)] (Cp=cyclopentadienyl) or Rh(2)(oct)(4), chemo and regioselective insertions of derived metal carbenes are achieved in favor of mono...

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Detalles Bibliográficos
Autores principales: Nikolova, Yana, Fabri, Bibiana, Moneva Lorente, Pau, Guarnieri‐Ibáñez, Alejandro, de Aguirre, Adiran, Soda, Yoshiki, Pescitelli, Gennaro, Zinna, Francesco, Besnard, Céline, Guénée, Laure, Moreau, Dimitri, Di Bari, Lorenzo, Bakker, Eric, Poblador‐Bahamonde, Amalia I., Lacour, Jérôme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9825994/
https://www.ncbi.nlm.nih.gov/pubmed/35943860
http://dx.doi.org/10.1002/anie.202210798

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