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Reductive Al−B σ‐Bond Formation in Alumaboranes: Facile Scission of Polar Multiple Bonds

We present facile access to an alumaborane species with electron precise Al−B σ‐bond. The reductive rearrangement of 1‐(AlI(2)), 8‐(BMes(2)) naphthalene (Mes=2,4,6‐Me(3)C(6)H(2)) affords the alumaborane species cyclo‐(1,8‐C(10)H(6))‐[1‐Al(Mes)(OEt(2))‐8‐B(Mes)] with a covalent Al−B σ‐bond. The Al−B...

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Detalles Bibliográficos
Autores principales:	Güven, Zeynep, Denker, Lars, Wullschläger, Daniela, Pablo Martínez, Juan, Trzaskowski, Bartosz, Frank, René
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826004/ https://www.ncbi.nlm.nih.gov/pubmed/35947518 http://dx.doi.org/10.1002/anie.202209502

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