Formation and Reactivity of a Fleeting Ni(III) Bisphenoxyl Diradical Species

Cytochrome P450s and Galactose Oxidases exploit redox active ligands to form reactive high valent intermediates for oxidation reactions. This strategy works well for the late 3d metals where accessing high valent states is rather challenging. Herein, we report the oxidation of Ni(II)(salen) (salen=N...

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Detalles Bibliográficos
Autores principales: Awasthi, Ayushi, Leach, Isaac F., Engbers, Silène, Kumar, Rakesh, Eerlapally, Raju, Gupta, Sikha, Klein, Johannes E. M. N., Draksharapu, Apparao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826141/
https://www.ncbi.nlm.nih.gov/pubmed/35978531
http://dx.doi.org/10.1002/anie.202211345

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826141/
https://www.ncbi.nlm.nih.gov/pubmed/35978531
http://dx.doi.org/10.1002/anie.202211345

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