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Formation and Reactivity of a Fleeting Ni(III) Bisphenoxyl Diradical Species
Cytochrome P450s and Galactose Oxidases exploit redox active ligands to form reactive high valent intermediates for oxidation reactions. This strategy works well for the late 3d metals where accessing high valent states is rather challenging. Herein, we report the oxidation of Ni(II)(salen) (salen=N...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826141/ https://www.ncbi.nlm.nih.gov/pubmed/35978531 http://dx.doi.org/10.1002/anie.202211345 |