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Arene Activation through Iminium Ions: Product Diversity from Intramolecular Photocycloaddition Reactions

While 2‐alk‐ω‐enyloxy‐sustituted benzaldehydes do not display any photochemical reactivity at the arene core, the respective iminium perchlorates were found to undergo efficient reactions either upon direct irradiation (λ=366 nm) or under sensitizing conditions (λ=420 nm, 2.5 mol% thioxanthen‐9‐one)...

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Detalles Bibliográficos
Autores principales: Proessdorf, Johanna, Jandl, Christian, Pickl, Thomas, Bach, Thorsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826208/
https://www.ncbi.nlm.nih.gov/pubmed/35920713
http://dx.doi.org/10.1002/anie.202208329