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Nitrene‐Mediated C−H Oxygenation: Catalytic Enantioselective Formation of Five‐Membered Cyclic Organic Carbonates

The synthesis of non‐racemic 5‐membered cyclic carbonates from abundant alcohols is reported. Conversion of the alcohol into an azanyl carbonate is followed by a chiral‐at‐ruthenium catalyzed cyclization to provide chiral cyclic carbonates in yields of up to 95 % and with up to 99 % ee. This new syn...

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Detalles Bibliográficos
Autores principales:	Nie, Xin, Ye, Chen‐Xi, Ivlev, Sergei I., Meggers, Eric
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9827974/ https://www.ncbi.nlm.nih.gov/pubmed/36184573 http://dx.doi.org/10.1002/anie.202211971

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