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Quantifying the Influence of Covalent Metal‐Ligand Bonding on Differing Reactivity of Trivalent Uranium and Lanthanide Complexes

Qualitative differences in the reactivity of trivalent lanthanide and actinide complexes have long been attributed to differences in covalent metal‐ligand bonding, but there are few examples where thermodynamic aspects of this relationship have been quantified, especially with U(3+) and in the absen...

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Detalles Bibliográficos
Autores principales: Fetrow, Taylor V., Zgrabik, Joshua, Bhowmick, Rina, Eckstrom, Francesca D., Crull, George, Vlaisavljevich, Bess, Daly, Scott R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828012/
https://www.ncbi.nlm.nih.gov/pubmed/36097137
http://dx.doi.org/10.1002/anie.202211145