Sulfenofunctionalization of Chiral α‐Trifluoromethyl Allylboronic Acids: Asymmetric Synthesis of SCF(3), SCF(2)R, SCN and SAr Compounds

We report herein a new method for the synthesis of densely functionalized chiral allyl SCF(3), SCF(2)R, SCN and SAr species with a separate CF(3) functionality. The synthetic approach is based on selenium‐catalyzed sulfenofunctionalization of chiral α‐CF(3) allylboronic acids. The reactions proceede...

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Detalles Bibliográficos
Autores principales: Wang, Qiang, Nilsson, Tomas, Eriksson, Lars, Szabó, Kálmán J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828052/
https://www.ncbi.nlm.nih.gov/pubmed/36152310
http://dx.doi.org/10.1002/anie.202210509

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828052/
https://www.ncbi.nlm.nih.gov/pubmed/36152310
http://dx.doi.org/10.1002/anie.202210509

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